Skip to main content
SpringerLink
Log in

A Carboxylic-Functionalized Anderson-Type Polyoxoanion for Efficient Selective Cationic Dye Adsorption

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

Organic dyes can inflict environmental harm and pose risks to human health, thereby presenting challenges in their treatment within industrial wastewater. Currently, numerous research groups have conducted investigations on the adsorption of organic dyes in industrial wastewater. Herein, this work focuses on the selective adsorption approach towards dyes molecules based on an Anderson-type polyoxometalate (noted as POM-1) as potential adsorbent, which has been functionalized with organic ligands to enhance its negative charge. Adsorption experiments revealed that POM-1 displayed efficient adsorption capabilities towards the cationic dye methyl blue with almost complete adsorption within 25 min, and the adsorption rate was calculated as 98%. A rapid and consecutive filtering experiments have also been performed and further proved the excellent adsorption behavior of POM-1 towards MB.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

Data Availability

No datasets were generated or analysed during the current study.

References

  1. X. Bai, J. Shi, Z. Y. Zhang, M. Hu, J. Chai, L. Xu, X. Jin, X. Shi, P. K. Jin, J. Clean. Prod. 138375, 421 (2023).

  2. F. X. Deng, E. Brillas, Sep. Purif. Technol. 123764, 316 (2023).

  3. H. Wu, Z. Z. Liu, A. Li, H. Yang, Chemosphere. 207, 174 (2017).

  4. R. M. Waliullah, A. I. Rehan, M. E. Awual, A. I. Rasee, Md. C. Sheikh, Md. S. Salman, M. S. Hossain, Md. M. Hasan, K. T. Kubra, Md. N. Hasan, H. M. Marwani, A. Islam, M. M. Rahman, M. M. Rahman, Md. R. Awual, J. Mol. Liq. 122763, 388 (2023).

  5. Md. S. Salman, Md. C. Sheikh, Md. M. Hasan, Md. N. Hasan, K. T. Kubra, A. I. Rehan, M. E. Awual, A. I. Rasee, R. M. Waliullah, M. S. Hossain, Md. A. Khaleque, A. K. D. Alsukaibi, H. M. Alshammari, Md. R. Awual, Appl. Surf. Sci. 157008, 622 (2023).

  6. A. I. Rehan, A. I. Rasee, M. E. Awual, R. M. Waliullah, M. S. Hossain, K. T. Kubra, Md. S. Salman, Md. M. Hasan, Md. N. Hasan, Md. C. Sheikh, H. M. Marwani, Md. A. Khaleque, A. Islam, Md. R. Awual, Colloids Surf. A Physicochem. Eng. Asp. 131859, 673 (2023).

  7. T. U. Rahman, H. Roy, A. Z. Shoronika, A. Fariha, M. Hasan, Md. S. Islam, H. M. Marwani, A. Islam, Md. M. Hasan, A. K. D. Alsukaibi, M. M. Rahman, Md. R. Awual, J. Mol. Liq. 122764, 388 (2023).

  8. H. Roy, T. U. Rahman, Md. A. J. R. Khan, Md. R. Al-Mamun, S. Z. Islam, Md. A. Khaleque, Md. I. Hossain, Md. Z. H. Khan, Md. S. Islam, H. M. Marwani, A. Islam, Md. M. Hasan, Md. R. Awual, J. Water Process. Eng. 104069, 54 (2023).

  9. A. Islam, S. H. Teo, Y. H. Taufiq-Yap, C. H. Ng, Dai-Viet N. Vo, M. L. Ibrahim, Md. M. Hasan, M. A. R. Khan, A. S. M. Nur, Md. R. Awual, Resour. Conserv. Recycl. 105849, 175 (2021).

  10. K. T. Kubra, Md. S. Salman, Md. N. Hasan, J. Mol. Liq. 115468, 328 (2021).

  11. K. T. Kubra, Md. S. Salman, H. Znad, Md. N. Hasan, J. Mol. Liq. 115541, 329 (2021).

  12. Md. M. Hasan, M.A. Shenashen, Md. N. Hasan, H. Znad, Md. S. Salman, Md. R. Awual, J. Mol. Liq. 114587, 323 (2021).

  13. Md. M. Hasan, Md. N. Hasan, Md. R. Awual, Md. M. Islam, M.A. Shenashen, J. Iqbal, J. Mol. Liq. 114356, 319 (2020).

  14. K. T. Kubra, Md. M. Hasan, Md. N. Hasan, Md. S. Salman, Md. A. Khaleque, Md. C. Sheikh, A. I. Rehan, A. I. Rasee, R.M. Waliullah, M. E. Awual, M. S. Hossain, A. K. D. Alsukaibi, H. M. Alshammari, Md. R. Awual, Colloids Surf. A Physicochem. Eng. Asp. 131415, 667 (2023).

  15. S. S. Wang , G. Y. Yang , Chem. Rev. 4962, 115 (2015).

  16. Z. J. Liu, X. L. Wang, C. Qin, Z. M. Zhang, Y. G. Li, W. L. Chen, E. B. Wang, Coord. Chem. Rev. 110, 313 (2016).

  17. J. J. Walsh, A. M. Bond, R. J. Forster, T. E. Keyes, Coord. Chem. Rev. 234, 306 (2016).

  18. C. Boskovic, Acc. Chem. Res. 2214, 50 (2019).

  19. J. X. Liu, X. B. Zhang, Y. L. Li, S. L. Huang, G. Y. Yang, Coord Chem Rev. 213260, 414 (2020).

  20. I. A. Weinstock, R. E. Schreiber, R. Neumann, Chem. Rev. 2717, 118 (2018).

  21. Z. K. Zhu, Y. Y. Lin, X. X. Li, D. Zhao, S. T. Zheng, Inorg. Chem. Front. 1302, 8 (2021).

  22. M. Stuckar, K. Y. Monakhov, Chem. Sci. 4376, 10 (2019).

  23. Y. Cheng, K. J. Qin, D. J. Zang, Rare Metals. 3600, 42 (2023).

  24. L. Chen, W. L. Chen, X. L. Wang, Y. G. Li , Z. M. Su, E. B. Wang, Chem. Soc. Rev. 284, 48 (2019).

  25. C. L. Wu, X. H. Qiao, C. M. Robertson, S. J. Higgins, C. X. Cai, R. J. Nichols, A. Vezzoli, Angew. Chem. Int. Ed. 12034, 59 (2020).

  26. G. X. Chi, D. Shuai, J. X. Li, X. S. Chen, H. Yang, M. J. Zhao, Z. D. Jiang, L. Wang, B. N. Chen, Nanoscale 14550, 35 (2023).

  27. A. Blazevic, A. Rompel, Coord Chem Rev. 64, 307 (2016).

  28. Q. H. Zhuang, Z. Q. Sun, C. G. Lin, B. Qi, Y. F. Song, Inorg. Chem. Front. 1711, 6 (2023).

  29. J. W. Zhang, Y. C. Huang, G. Li, Y. G. Wei, Coord Chem Rev. 414, 378 (2019).

  30. X. X. Li, Y. X. Wang, R. H. Wang, C. Y. Cui, C. B. Tian, G. Y. Yang, Angew. Chem. Int. Ed. 6466, 55 (2016).

  31. J. W. Zhang, Y. C. Huang, J. Hao, Y. G. Wei, Inorg. Chem. Front. 1218, 7 (2017).

  32. H. K. Yang, K. Wang, C. Zhang, H. Zhang, J. Mater. Sci. 5425, 57 (2022).

  33. Y. Zhang, X. Wang, Y. Wang, L. Li, N. Xu, X. L. Wang, Inorg. Chem. Front. 4466, 20 (2021).

  34. Y. S. Li, M. X. Liu, L. Chen, J. Mater. Chem. A. 13762, 26 (2017).

  35. Md. R. Awual, Chem. Eng. J. 85, 307 (2017).

  36. Md. S. Salman, Md. N. Hasan, Md. M. Hasan, K. T. Kubra, Md. C. Sheikh, A. I. Rehan, R. M. Waliullah, A. I. Rasee, M. E. Awual, M. S. Hossain, A. K. D. Alsukaibi, H. M. Alshammari, Md. R. Awual, J. Mol. Struct. 135259, 1282 (2023).

  37. A. Shahat, K. T. Kubra, Md. S. Salman, Md. N. Hasan, Md. M. Hasan, Microchem. J. 105967, 164 (2021).

  38. Md. R. Awual, Md. M. Hasan, Md. A. Khaleque, Md. C. Sheikh, Chem. Eng. J. 368, 288 (2016).

  39. Md. R. Awual, Md. M. Hasan, M. M. Rahman, A. M. Asiri, J. Mol. Liq. 772, 283 (2019).

  40. M. P. Merkel, C. E. Anson, G. E. Kostakis, A. K. Powell, Cryst. Growth Des. 3190, 21 (2021).

  41. Md. R. Awual, Compos. B. Eng. 387, 172 (2019).

  42. Md. R. Awual, J. Clean. Prod. 1311, 228 (2019).

  43. Md. R. Awual, Md. M. Hasan, A. Islam, M. M. Rahman, A. M. Asiri, Md. A. Khaleque, Md. C. Sheikh, J. Clean. Prod. 778, 228 (2019).

  44. Md. R. Awual, J. Mol. Liq. 502, 284 (2019).

  45. M. E. Awual, Md. S. Salman, Md. M. Hasan, Md. N. Hasan, K. T. Kubra, Md. C. Sheikh, A. I. Rasee, A. I. Rehan, R. M. Waliullah, M. S. Hossain, Md. A. Khaleque, Md. R. Awual, J Ind Eng Chem. 585, 131 (2024).

  46. Md. C. Sheikh, Md. M. Hasan, Md. N. Hasan, Md. S. Salman, K. T. Kubra, A. Islam, Md. A. Khaleque, Md. R. Awual, J. Mol. Liq. 122854, 389 (2023).

  47. A. I. Rasee, E. Awual, A. I. Rehan, A. Islam, Md. A. Khaleque, Md. R. Awual, Surf. Interfaces. 103276 (2023).

  48. Md. R. Awual, Md. N. Hasan, Md. M. Hasan, Md. S. Salman, Md. C. Sheikh, K. T. Kubra, A. I. Rasee, M. E. Awual, Sep. Purif. Technol. 124088, 319 (2023).

  49. Md. M. Hasan, Md. S. Salman, Md. N. Hasan, A. I. Rehan, A. Islam, Md. R. Awual, Colloids Surf. A Physicochem. Eng. Asp. 131794, 673 (2023).

  50. K. T. Kubra, Md. M. Hasan, Md. N. Hasan, A. K. D. Alsukaibi, H. M. Alshammari, Md. R. Awual, Colloids Surf. A Physicochem. Eng. Asp. 131415, 667 (2023).

  51. J. W. Han, C. L. Hill, J. Am. Chem. Soc. 15095, 129 (2007).

  52. Sara Dawood, Tushar Kanti Sen, Water Res. 1946, 46 (2012).

Download references

Funding

This work was co-financed by National Natural Science Foundation of China (21901147) and Natural Science Foundation of Shandong Province (ZR2023MB035).

Author information

Author notes

  1. Hongji Kang and Lili Yang contributed equally to this work.

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Shandong University of Technology, Zibo, 255000, People’s Republic of China

    Hongji Kang, Yuqi Liu, Hao Zhang, Xiaoxue Huang & Lu Yang

  2. Shangqiu Product Quality Inspection and Research Center, Shangqiu, 476000, People’s Republic of China

    Lili Yang & Ke Su

Authors
  1. Hongji Kang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Lili Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yuqi Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Ke Su
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Hao Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Xiaoxue Huang
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Lu Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

Lu Yang conceived and designed the experiments, and funding acquisition. Hongji Kang performed the experiments and wrote the paper. Lili Yang contributed measurement and technical support. Yuqi Liu, Ke Su, Hao Zhang and Xiaoxue Huang assisted the formal analysis and investigation. All authors discussed the results and commented on the manuscript.

Corresponding author

Correspondence to Lu Yang.

Ethics declarations

Ethical Approval

Not applicable.

Competing Interests

The authors declare no competing interests.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (DOCX 1162 KB)

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Kang, H., Yang, L., Liu, Y. et al. A Carboxylic-Functionalized Anderson-Type Polyoxoanion for Efficient Selective Cationic Dye Adsorption. J Clust Sci (2024). https://doi.org/10.1007/s10876-024-02601-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • DOI: https://doi.org/10.1007/s10876-024-02601-4

Keywords

Search

Navigation