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Syntheses, Characterizations and Properties of [Mo2O2S2]-Based Oxothiomolybdenum Rings Incorporating Carboxylate Ligands

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Abstract

Three cyclic polyoxothiomolybdates [Mo20O20S20(OH)20(PyD)2]4− (1) (PyD2− = 3,5-pyridinedicarboxylic acid, C7H6O4N2−), [Mo12O12S12(OH)12(H2O)5(NapH)]2− (2) (NapH2− = 1,4-naphthalene dicarboxylic acid, C12H6O42−) and [Mo8O8S8(OH)8(Ox)]2− (3) (Ox2− = oxalic acid, C2O42−) have been obtained from the condensation of the [Mo2O2S2]2+ building block in the presence of PyD2−, NapH2− and Ox2−, respectively. Compounds 1 − 3 were characterized by FT-IR spectroscopy, powder X-ray diffraction, UV–visible spectroscopy and thermogravimetric analysis. The structures of compounds 1 − 3 have been unambiguously established by single crystal X-ray crystallography. The electrochemical behaviors in DMF observed for three oxothiomolybdenum rings evidenced the ability to function as efficient electrocatalysts toward the reduction of protons into hydrogen.

Graphical Abstract

Three cyclic polyoxothiomolybdates self-assembled around carboxylate ligands were synthesized and characterized. The complexes showed electrocatalytic performance for HER in nonaqueous condition.

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (No. 21471003 and 21372007); Natural Science Foundation of Educational Commission of Anhui Province of China (No. KJ2020A0240).

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  1. Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, 243002, Anhui, People’s Republic of China

    Qian-Ya Xu, Zhifeng Xin, Meng-Jie Hu, Hua-Tian Shi, Ai-Quan Jia & Qian-Feng Zhang

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Xu, QY., Xin, Z., Hu, MJ. et al. Syntheses, Characterizations and Properties of [Mo2O2S2]-Based Oxothiomolybdenum Rings Incorporating Carboxylate Ligands. J Clust Sci 34, 285–295 (2023). https://doi.org/10.1007/s10876-022-02219-4

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