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Assembly of Organic–Inorganic Hybrids From 1D to 2D Framework Based on Triethanolamine-Functionalized Molybdovanadate with Electrochemical Sensing of Ascorbic Acid

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Abstract

Two new organic–inorganic hybrids, (TeaH)2[Cu(Tea)(H2O)2]2[Cu(Tea)]2[HN(CH2CH2O)3VMo6O22]2·12H2O (1), (NH4)5[Na(H2O)2][Cu(Tea)]2[HN(CH2CH2O)3VMo6O22]2·13H2O (2) [Tea = triethanolamine], has been synthesized and structurally characterized. A hybrid subunit [HN(CH2CH2O)3VMo6O22]5− was synthesized in aqueous solution, in which Tea ligand is linked covalently with the [VMo6O25]9− cluster. In compound 1, the {[Cu(Tea)]2[HN(CH2CH2O)3VMo6O22]2}6− anions, [Cu(Tea)(H2O)2] units and protonated [TeaH]+ cations are joined together via hydrogen bond interactions to form a two-dimensional (2D) layered framework. Compound 2 adopts a 1D chain structure, in which the adjacent {[Cu(Tea)]2[HN(CH2CH2O)3VMo6O22]2}6− anions are connected alternately by [Na(H2O)2]+ units. Compounds 1 and 2 modified electrodes exhibit good electrochemical sensing performance for the detection of ascorbic acid.

Graphic Abstract

Two new organic-inorganic hybrids from 1D to 2D framework based on triethanolamine functionalized molybdovanadate have been synthesized and structurally characterized. The functional application of 1 and 2 in electrochemical sensing of AA are investigated in detail.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Grant No. 81973468 and 81803680), Jilin Province Science and Technology Development Project in China (Grant No. 20170309005YY), "Xinglin Scholars Project" Young Scientist Training Program of Changchun University of Chinese Medicine.

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Authors and Affiliations

  1. School of Pharmaceutical Sciences, Changchun University of Chinese Medicine, Changchun, 130117, People’s Republic of China

    Da Liu, Hao-Ming Luo & Qiao Gao

  2. Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Lin Xu

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  1. Da Liu
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  2. Hao-Ming Luo
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  4. Lin Xu
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Correspondence to Qiao Gao.

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Liu, D., Luo, HM., Gao, Q. et al. Assembly of Organic–Inorganic Hybrids From 1D to 2D Framework Based on Triethanolamine-Functionalized Molybdovanadate with Electrochemical Sensing of Ascorbic Acid. J Clust Sci 32, 1381–1387 (2021). https://doi.org/10.1007/s10876-020-01897-2

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