Abstract
The present paper reports an unexplored simple, single step and cost effective green process for the preparation of highly stable silver nanoparticles (AgNPs) using Epilobium parviflorum (EP) extract and investigates their catalytic activity towards hazardous organic dyes, congo red (CR), rhodamine B (RhB), methyl orange (MO), methyl red (MR), and colorimetric sensing ability for Hg2+ ions in solutions. Attenuated Total Reflectance Fourier Transform Infrared spectroscopy (ATR–FTIR) studies confirmed the capping and stabilization of the AgNPs by EP extract. X-ray diffraction (XRD) pattern showed face centered cubic structure for the AgNPs. Transmission electron microscopy (TEM) validated that the AgNPs are spherical in shape with narrow size distribution of 5.59 ± 1.12 nm. The results indicate that regardless of their good linear dynamic range (0.5–5.0 µM), detection limit (58.11 nM, 11.62 ppb) and selectivity for the accurate determination of Hg2+ ions, the AgNPs can be attractive choices for wastewater management systems.
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10876-019-01634-4/MediaObjects/10876_2019_1634_Fig1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10876-019-01634-4/MediaObjects/10876_2019_1634_Sch1_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10876-019-01634-4/MediaObjects/10876_2019_1634_Fig2_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10876-019-01634-4/MediaObjects/10876_2019_1634_Fig3_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10876-019-01634-4/MediaObjects/10876_2019_1634_Fig4_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10876-019-01634-4/MediaObjects/10876_2019_1634_Fig5_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10876-019-01634-4/MediaObjects/10876_2019_1634_Fig6_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10876-019-01634-4/MediaObjects/10876_2019_1634_Fig7_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10876-019-01634-4/MediaObjects/10876_2019_1634_Fig8_HTML.png)
![](http://media.springernature.com/m312/springer-static/image/art%3A10.1007%2Fs10876-019-01634-4/MediaObjects/10876_2019_1634_Fig9_HTML.png)
Similar content being viewed by others
References
V. K. Sharma, R. A. Yngard, and Y. Lin (2009). Adv. Coll. Interface. Sci. 145, 83.
V. Annavaram, V. R. Posa, V. G. Uppara, S. Jorepalli, and A. R. Somala (2015). BioNanoScience 5, 97.
M. Li, X. Huang, and H. Yu (2019). Mater. Sci. Eng., C 101, 614.
M. Zhao, H. Yu, and Y. He (2019). Sens. Actuat. B Chem. 283, 329.
J. Du, M. Zhao, W. Huang, Y. Deng, and Y. He (2018). Anal. Bioanal. Chem. 410, 4519.
W. Huang, Y. Deng, and Y. He (2017). Biosens. Bioelectron. 91, 89.
G. Elmacı, A. S. Ertürk, M. Sevim, and Ö. Metin (2019). Int. J. Hydrogen Energy 44, 17995.
A. S. Ertürk and G. Elmacı (2018). J. Inorg. Organomet. Polym Mater. 28, 2100.
M. U. Gürbüz and A. S. Ertürk (2018). J. Turkish Chem. Soc. Sec. A Chem. 5, 885.
S. Ahmed, M. Ahmad, B. L. Swami, and S. Ikram (2016). J. Adv. Res. 7, 17.
Y. He, B. Xu, W. Li, and H. Yu (2015). J. Agric. Food Chem. 63, 2930.
Y. Zhou, W. Huang, and Y. He (2018). Sens. Actuat. B Chem. 270, 187.
L. Wei, J. Lu, H. Xu, A. Patel, Z.-S. Chen, and G. Chen (2015). Drug Discov. Today 20, 595.
H. Veisi, S. Azizi, and P. Mohammadi (2018). J. Cleaner Prod. 170, 1536.
N. Durán, P. D. Marcato, M. Durán, A. Yadav, A. Gade, and M. Rai (2011). Appl. Microbiol. Biotechnol. 90, 1609.
M. Ovais, I. Ahmad, A. T. Khalil, S. Mukherjee, R. Javed, M. Ayaz, et al (2018). Appl. Microbiol. Biotechnol. 1.
T. Bajer, D. Silha, K. Ventura, and P. Bajerova (2017). Ind. Crops Prod. 100, 95.
A. K. Kiss, A. Bazylko, A. Filipek, S. Granica, E. Jaszewska, U. Kiarszys, et al. (2011). Phytomedicine 18, 557.
V. Kumar, S. Mohan, D. K. Singh, D. K. Verma, V. K. Singh, and S. H. Hasan (2017). Mater. Sci. Eng., C 71, 1004.
N. A. Khan, A. Niaz, M. I. Zaman, F. A. Khan, and M. Tariq (2018). Mater. Res. Bull. 102, 330.
L. B. Anigol, J. S. Charantimath, and P. M. Gurubasavaraj (2017). Org. Med. Chem. 3, 1.
S. P. Dubey, M. Lahtinen, and M. Sillanpää (2010). Process Biochem. 45, 1065.
S. M. Roopan, G. Madhumitha, A. A. Rahuman, C. Kamaraj, A. Bharathi, and T. Surendra (2013). Ind. Crops Prod. 43, 631.
K. S. Chou, Y. C. Lu, and H. H. Lee (2005). Mater. Chem. Phys. 94, 429.
F. Samari, H. Salehipoor, E. Eftekhar, and S. Yousefinejad (2018). New J. Chem. 42, 15905.
M. Li, S. K. Cushing, and N. Wu (2015). Analyst 140, 386.
J. P. Oliveira, A. R. Prado, W. J. Keijok, M. R. N. Ribeiro, M. J. Pontes, B. V. Nogueira, et al (2017). Arabian J. Chem.
P. Song, J.-J. Feng, F.-Y. Guo, and A.-J. Wang (2015). J. Mater. Chem. A 3, 15920.
V. Kumar, D. K. Singh, S. Mohan, D. Bano, R. K. Gundampati, and S. H. Hasan (2017). J. Photochem. Photobiol., B 168, 67.
W. R. Rolim, M. T. Pelegrino, B. de Araujo Lima, L. S. Ferraz, F. N. Costa, J. S. Bernardes, et al. (2019). Appl. Surf. Sci. 463, 66.
A. Rostami-Vartooni, M. Nasrollahzadeh, and M. Alizadeh (2016). J. Colloid Interface Sci. 470, 268.
M. Ismail, M. I. Khan, K. Akhtar, M. A. Khan, A. M. Asiri, and S. B. Khan (2018). Phys. E (Amsterdam Neth) 103, 367.
M. A. Pantoja-Castro and H. González-Rodríguez (2011). Revista Latinoamericana de Química 39, 107.
N. Baert, M. Karonen, and J. P. Salminen (2015). J. Chromatogr. A 1419, 26.
S. Granica, J. P. Piwowarski, M. E. Czerwinska, and A. K. Kiss (2014). J. Ethnopharmacol. 156, 316.
I. Remmel, L. Vares, L. Toom, V. Matto, and A. Raal (2012). Nat. Prod. Commun. 7, 1323.
B. H. Tóth, A. Balázs, V. Vukics, É. Szőke, and Á. Kéry (2006). Chromatographia 63, S119.
B. Khodadadi, M. Bordbar, and M. Nasrollahzadeh (2017). J. Colloid Interface Sci. 493, 85.
E. Priyadarshini and N. Pradhan (2017). Sens. Actuat. B Chem. 238, 888.
P. B. Tchounwou, W. K. Ayensu, N. Ninashvili, and D. Sutton (2003). Environ. Toxicol. Int. J. 18, 149.
M. Li, H. Gou, I. Al-Ogaidi, N. Wu, Nanostructured sensors for detection of heavy metals: a review (ACS Publications, 2013).
K. Farhadi, M. Forough, R. Molaei, S. Hajizadeh, and A. Rafipour (2012). Sens. Actuat. B Chem. 161, 880.
V. Marimuthu, S. Chandirasekar, and N. Rajendiran (2018). ChemistrySelect 3, 3918.
M. Sebastian, A. Aravind, and B. Mathew (2018). Nanotechnology 29, 355502.
C. Tagad, H. H. Seo, R. Tongaonkar, Y. W. Yu, J. H. Lee, M. Dingre, et al. (2017). Sens. Mater. 29, 205.
M. Sengan, D. Veeramuthu, and A. Veerappan (2018). Mater. Res. Bull. 100, 386.
I. Uddin, K. Ahmad, A. A. Khan, and M. A. Kazmi (2017). Sens. Bio-Sens. Res. 16, 62.
S. S. Ravi, L. R. Christena, N. SaiSubramanian, and S. P. Anthony (2013). Analyst 138, 4370.
A. Devadiga, K. Vidya Shetty, and M. B. Saidutta (2017). Mater. Lett. 207, 66.
M. McDonald, I. Mila, and A. Scalbert (1996). J. Agric. Food Chem. 44, 599.
E. Giannakopoulos, P. Stathi, K. Dimos, D. Gournis, Y. Sanakis, and Y. Deligiannakis (2006). Langmuir 22, 6863.
D. Karthiga and S. P. Anthony (2013). RSC Adv. 3, 16765.
X. Yang, J. D. Ranford, and J. J. Vittal (2004). Cryst. Growth Des. 4, 781.
V. Vinod Kumar and S. P. Anthony (2014). Sens. Actuat. B Chem. 191, 31.
E. Terenteva, V. Apyari, E. Kochuk, S. Dmitrienko, and Y. A. Zolotov (2017). J. Anal. Chem. 72, 1138.
G. V. Ramesh and T. P. Radhakrishnan (2011). ACS Appl. Mater. Interfaces 3, 988.
N. Y. Nadaf, S. S. Kanase (2016). Arabian J. Chem.
K. Jyoti and A. Singh (2016). J. Genetic Eng. Biotechnol. 14, 311.
T. Rasheed, M. Bilal, C. Li, F. Nabeel, M. Khalid, and H. M. Iqbal (2018). J. Photochem. Photobiol., B 181, 44.
U. Kurtan, M. Amir, A. Yıldız, and A. Baykal (2016). Appl. Surf. Sci. 376, 16.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
The author declares that they have no conflict of interest.
Additional information
Publisher's Note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Ertürk, A.S. Biosynthesis of Silver Nanoparticles Using Epilobium parviflorum Green Tea Extract: Analytical Applications to Colorimetric Detection of Hg2+ Ions and Reduction of Hazardous Organic Dyes. J Clust Sci 30, 1363–1373 (2019). https://doi.org/10.1007/s10876-019-01634-4
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10876-019-01634-4