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Supramolecular Adduct of γ-Cyclodextrin and [{Re6Q8}(H2O)6]2+ (Q=S, Se)

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Abstract

Slow evaporation of water solution of [{Re6S8}(H2O)6]2+ generated in situ from [{Re6S8}(OH)6]4– in presence of γ-cyclodextrin (CD) leads to crystallization of {[{Re6S8}(H2O)6] ⊂ [γ-CD]}(NO3)2·12H2O (1·12H2O) supramolecular complex, which was characterized by single-crystal X-ray diffraction crystallography, IR-spectroscopy, thermogravimetric and elemental analyses. X-ray analysis confirms the formation of 1:1 {[{Re6S8}(H2O)6] ⊂ [γ-CD]}2+ inclusion compound in the solid state. However, no adduct formation was detected between [{Re6S8}(H2O)6]2+ and γ-cyclodextrin in solution, according to 1H NMR spectroscopy. In the case of in situ generated [{Re6Se8}(H2O)6]2+ the reaction solution with γ-cyclodextrin is unstable and during the crystallization only amorphous precipitate has been obtained.

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Acknowledgements

This work was supported by Russian Foundation for Basic Research (Grant Number 17-53-16006) and LIA-CNRS 1144 CLUSPOM.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry SB RAS, Novosibirsk, Russian Federation, 630090

    Pavel A. Abramov, Anton A. Ivanov, Michael A. Shestopalov & Maxim N. Sokolov

  2. Novosibirsk State University, Novosibirsk, Russian Federation, 630090

    Pavel A. Abramov, Michael A. Shestopalov & Maxim N. Sokolov

  3. Institut Lavoisier de Versailles, CNRS, Université de Versailles, Versailles, 78035, France

    Mhamad A. Moussawi, Emmanuel Cadot, Sébastien Floquet & Mohamed Haouas

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  1. Pavel A. Abramov
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Abramov, P.A., Ivanov, A.A., Shestopalov, M.A. et al. Supramolecular Adduct of γ-Cyclodextrin and [{Re6Q8}(H2O)6]2+ (Q=S, Se). J Clust Sci 29, 9–13 (2018). https://doi.org/10.1007/s10876-017-1312-z

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