Abstract
Three title metal complexes of [Cu(H2O)4(CH3COO)2(H2L)2] (1), [(Mn(H2L))2Cl4(H2O).5(H2O)] (2) and [Cu3(CH3COO)2(CH3OH)(H2L)2] (3) have been synthesized and characterized by X-ray single-crystal analyses, elemental analysis, infrared spectrum, UV–Vis absorption spectra and fluorescence spectra, which are based on a flexible ligand 3,5-dibromosalicylaldehyde diethylenetriamine (H2L) by diffusion method. Crystallographic analysis show that for complex 1, the infinite 1D square sheets arrange regularly to form 2D channels by O–H⋯O bonds, complex 2 can form 2D spatial structure through the coordination effect, π–π accumulation effect, van der Waals force and intermolecular weak H-bonds, complex 3 is self-assembled via intermolecular π–π stacking, van der Weals force and intermolecular weak H-bonds with various coordination modes of center Cu ions.
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Acknowledgments
This work was supported by the National Nature Science Foundation of China (21266006, 61301038, 61271119), and the Nature Science Foundation of Guangxi Province (No.2012GXNSFAA053034).
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Lai, LY., Liu, Z., Han, GC. et al. Synthesis, Crystal Structure and Properties of Three Metal Complexes Based on a Flexible Schiff Base Ligand. J Clust Sci 26, 1845–1855 (2015). https://doi.org/10.1007/s10876-015-0883-9
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DOI: https://doi.org/10.1007/s10876-015-0883-9