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Assembly of Supramolecular Networks with the Inclusion of T4(2)6(2) Water Tapes and R6 Water Clusters

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Abstract

Two new supramolecular compounds were synthesized and characterized with the formula of [Cu(bipy)2(OAc)]·(DBrS)1/2·5H2O 1, [Co(phen)2(CO3)]·(DBrS)1/2·5H2O 2 (H2DBS = meso-2,3-dibromosuccinic acid; bipy = 2,2’-bipyridine; phen = 1,10-phenanthroline). The crystal structures of complexes were determined by X-ray single-crystal diffraction. Complex 1 represents R6 water clusters and complex 2 stabilizes in a 1D water tape notated T4(2)6(2). For 2, the 2D layer is defined as a 2D (3,4,6)-connected network with the Schläfli symbol of (4·5·6)4(42·5·6·72)(42·5)2(44·52·62·74·93). Results about i.r. spectra and elemental analyses are presented.

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Acknowledgments

The honest thanks are also extended to K. C. Wong Magna Fund in Ningbo University.

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Authors and Affiliations

  1. Research Center for Solid State Chemistry & Application, Ningbo University, Ningbo, 315211, People’s Republic of China

    Wan-Dan Weng, Yue-Qing Zheng, Hong-Lin Zhu & Jian-Qing Xu

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  1. Wan-Dan Weng
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  2. Yue-Qing Zheng
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  3. Hong-Lin Zhu
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Correspondence to Yue-Qing Zheng.

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Weng, WD., Zheng, YQ., Zhu, HL. et al. Assembly of Supramolecular Networks with the Inclusion of T4(2)6(2) Water Tapes and R6 Water Clusters. J Clust Sci 26, 1833–1843 (2015). https://doi.org/10.1007/s10876-015-0882-x

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  • DOI: https://doi.org/10.1007/s10876-015-0882-x

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