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Synthesis, Structures and Luminescent Properties of 3D Copper(I) 1,2,4-Triazolates Containing Cubic Cu4X4 Clusters (X = Cl, Br)

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Abstract

Reactions of 3,5-disubstituted-1,2,4-triazoles with CuX2 (X = Cl, Br) under hydrothermal condition yield six copper(I) triazolates: [Cu2(3,5-nBu2tz)Cl]n (1), [Cu2(3,5-iBu2tz)Cl]n (2), {Cu2(3,5-(C6H11)2tz)Cl}n (3), [Cu2(3,5-sBu2tz)Br]n (4), {Cu2(3,5-(C6H11)2tz)Br}n (5), {Cu2[3,5-(p-Tol)2tz]Br}n (6), where 3,5-nBu2tz, 3,5-iBu2tz, 3,5-sBu2tz are 3,5-dibutyl-1,2,4-triazolate, 3,5-dii-butyl-1,2,4-triazolate, 3,5-dis-butyl-1,2,4-triazolate; 3,5-(C6H11)2tz is 3,5-dicyclohexyl-1,2,4-triazolate; 3,5-(p-Tol)2tz is 3,5-di-p-tolyl-1,2,4-triazolate. X-ray analysis demonstrates that all of these complexes are isostructural and exhibit a 3D structure carrying cubic Cu4Cl4 or Cu4Br4 clusters. While 4 and 5 luminesce with maxima at 571 and 619 nm, others are silent under UV irradiation at room temperature.

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Acknowledgments

This work has been supported by the NSF of China (Nos. 21471132, 21071126, J1210060).

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Authors and Affiliations

  1. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001, China

    Ze-Jie Lv, Xiu-Bao Wei & Guang Yang

  2. Analysis & Test Laboratory, Department of Basic Medical Science, Xinxiang Medical University, Xinxiang, 453000, China

    Ping-Ning Jin

  3. The Centre of Supervision and Inspection of Quality and Technique at Sanmenxia, Sanmenxia, 472000, China

    Yong-Hui Wang

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  1. Ze-Jie Lv
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  2. Ping-Ning Jin
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  3. Yong-Hui Wang
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Correspondence to Guang Yang.

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Lv, ZJ., Jin, PN., Wang, YH. et al. Synthesis, Structures and Luminescent Properties of 3D Copper(I) 1,2,4-Triazolates Containing Cubic Cu4X4 Clusters (X = Cl, Br). J Clust Sci 26, 1389–1401 (2015). https://doi.org/10.1007/s10876-014-0821-2

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