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Syntheses and crystal structures of four silver(I) complexes of 4-amino-3,5-dicyclohexyl-1,2,4-triazole or 3,5-dicyclohexyl-1,2,4-triazolate: observation of Agtz3 and Ag4tz4 structural motifs

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Abstract

Three novel Ag(I) adducts with 4-amino-3,5-dicyclohexyl-1,2,4-triazole [4-NH2-3,5-(C6H11)2tz], namely {Ag2[4-NH2-3,5-(C6H11)2tz]2(NO3)2} (1), {Ag4[4-NH2-3,5-(C6H11)2tz]4(ClO4)2}(ClO4)2 (2), {Ag[4-NH2-3,5-(C6H11)2tz]3}(ClO4) (3), as well as one polymeric Ag(I) triazolate, {Ag3[3,5-(C6H11)2tz]2(NO3)} n (4), have been synthesized and characterized. X-ray analyses show that 1–3 are discrete dinuclear, cyclic tetranuclear and mononuclear complexes, featuring Ag2tz2, Ag4tz4 and Agtz3 structural motifs in turn. 4 is a 3D coordination polymer with the Ag4tz4 clusters as the secondary building unit, the ant network can be extracted from the structure of 4.

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Acknowledgments

This work has been supported by the NSF of China (21071126 and J1210060).

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Authors and Affiliations

  1. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001, China

    Ya-Mei Liu, Shi-Tu Yang, Ting-Ting Yan, Hui Yang, Xiu-Bao Wei & Guang Yang

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  1. Ya-Mei Liu
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  2. Shi-Tu Yang
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  3. Ting-Ting Yan
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  4. Hui Yang
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  5. Xiu-Bao Wei
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  6. Guang Yang
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Correspondence to Guang Yang.

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Liu, YM., Yang, ST., Yan, TT. et al. Syntheses and crystal structures of four silver(I) complexes of 4-amino-3,5-dicyclohexyl-1,2,4-triazole or 3,5-dicyclohexyl-1,2,4-triazolate: observation of Agtz3 and Ag4tz4 structural motifs. Transition Met Chem 38, 543–551 (2013). https://doi.org/10.1007/s11243-013-9722-8

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