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Synthesis, Crystal Structure, and Dielectric Properties of (3-Aminopropyl-imidazolium) Pentachlorobismuthate (III) [C6H13N3]BiCl5

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Abstract

A new organic–inorganic hybrid material of formula [C6H13N3]BiCl5 was synthesized and characterized by X-ray diffraction. This compound crystallizes in the monoclinic system with space group P21/n. The unit cell dimensions are a = 10.287(5) Å, b = 13.845(7) Å, c = 10.605(6) Å and β = 108.46(3)° with Z = 2. The atomic arrangement can be described as an alternation of organic and inorganic layers. The anionic layer is built up of bioctahedral [Bi2Cl10]4− arranged in sandwich between the organic ones. The crystal packing is governed by means of the N–H···Cl hydrogen bonds, forming a three dimensional network. Differential scanning calorimetry and thermogravimetric analysis disclose structural phase transition of order–disorder type at 465 K. Dielectric investigations revealed a step-wise change of the electric permittivity at Ttr1 characteristic of the crystal in the high-temperature phase. The evolution of dielectric constant as a function of temperature of the sample has been investigated in order to determine some related parameters. Solid-state 13C MAS NMR spectroscopy results are in agreement with the X-ray structure.

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Acknowledgments

The crystal data collection of the title compound was done in the “Department of Chemistry, Faculty of Sciences of Sfax, University of Sfax, BP 1171, 3038 Sfax, Tunisia”. We are grateful to Abdelhamid Ben Salah who supervised this experiment. The spectrum Raman was done in “Laboratory of ferroelectric materials, Faculty of Sciences of Sfax, University of Sfax, BP 1171, 3038 Sfax, Tunisia. We grateful to Hamadi Khemkhem who supervised this experiment.

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  1. Laboratoire des Sciences des Matériaux et d’Environnement, Faculté des Sciences de Sfax, Université de Sfax, BP 1171, Route de Soukra, 3018, Sfax, Tunisia

    Sassi Attia, Najla Chaari & Slaheddine Chaabouni

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  1. Sassi Attia
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  2. Najla Chaari
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  3. Slaheddine Chaabouni
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Correspondence to Sassi Attia.

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Attia, S., Chaari, N. & Chaabouni, S. Synthesis, Crystal Structure, and Dielectric Properties of (3-Aminopropyl-imidazolium) Pentachlorobismuthate (III) [C6H13N3]BiCl5 . J Clust Sci 26, 1343–1359 (2015). https://doi.org/10.1007/s10876-014-0818-x

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