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Amino Acid Functionalization of {Ni6PW9}-Based Clusters Under Hydrothermal Conditions

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Abstract

Two novel hexa-nickel(II)-substituted Keggin-type {Ni6PW9}-based tungstophosphates [Ni6(μ 3-Tris)(en)3(Pr)(damp)(H2O)2(B-α-PW9O34)]·10H2O (1) and [Ni6(μ 3-Tris)(en)3(damp)2(H2O)2(B-α-PW9O34)]·7H2O (2) (en = ethylenediamine, Pr = CH3CH2COO−, damp = 2-aminoisobutyrate, Tris = pentaerythritol) were hydrothermally synthesized and characterized by IR spectra, elemental analyses, powder X-ray diffraction, thermogravimetric analyses, and single-crystal X-ray diffraction. Crystal data for 1: orthorhombic, Pca21, a = 21.6962(7) Å, b = 20.6398(5) Å, c = 14.7825(4) Å, β = 90º, V = 6619.7(3) Å3, Z = 4; for 2: orthorhombic, Pca21, a = 21.6978(9) Å, b = 20.6658(7) Å, c = 14.7767(4) Å, β = 90º, V = 6625.9(4) Å3, Z = 4. 1 consists of a {Ni6(μ 3-Tris)(en)3(Pr)(damp)(H2O)2}9+ core and a [B-α-PW9O34]9− (PW9) unit and is covalently functionalized by one Pr and one damp, as well as en and Tris ligands. The structure of 2 is the same to 1 except that the Pr anion in 1 is substituted by the other damp ligand. Most interestingly, 1 contains four kinds of organic ligands, while 2 includes three kinds of organic ligands, which are first observed in polyoxometalate chemistry.

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Acknowledgments

This work was supported by the NNSF of China (nos. 91122028, 21221001, 50872133, 21101055, 21301049 and U1304208), the NNSF for Distinguished Young Scholars of China (no. 20725101), and the 973 program (nos. 2014CB932101 and 2011CB932504).

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Authors and Affiliations

  1. MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing, 100081, China

    Bin Cai, Bai-Feng Yang, Huan He & Guo-Yu Yang

  2. Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, Henan, China

    Jun-Wei Zhao

  3. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, Fujian, China

    Guo-Yu Yang

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  1. Bin Cai
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  2. Bai-Feng Yang
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  3. Huan He
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Correspondence to Jun-Wei Zhao or Guo-Yu Yang.

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Cai, B., Yang, BF., He, H. et al. Amino Acid Functionalization of {Ni6PW9}-Based Clusters Under Hydrothermal Conditions. J Clust Sci 25, 1283–1293 (2014). https://doi.org/10.1007/s10876-014-0706-4

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  • DOI: https://doi.org/10.1007/s10876-014-0706-4

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