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A New Organic-Paradodecatungstate Hybrid Compound: Synthesis, Characterization and Crystal Structure

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Abstract

An organic–inorganic hybrid compound Na2(HAn)8[H2W12O42]·16H2O (HAn: p-anisidinium, C7H10NO) has been synthesized under soft acidic conditions and characterized by infrared and UV–visible spectroscopies, thermogravimetric analysis, cyclic voltammetry and single crystal X-ray diffraction. The compound crystallizes in the monoclinic P21/n space group with a = 10.1920(4) Å, b = 34.2901(9) Å, c = 14.0745(5) Å, β = 95.830(3)°, V = 4,893.4(3) Å3 and Z = 4. The compound exhibits a 2D supramolecular structure formed by alternated [paradodecatungstate/Na] and p-anisidinium layers. The catalytic activity of the compound for oxidation of cyclooctene with H2O2 was proved and gives rise to good reaction yield.

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Acknowledgments

This work was supported by the Ministry of Higher Education and Scientific Research of Tunisia.

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Authors and Affiliations

  1. Laboratoire des Matériaux et Cristallochimie (LMC), Institut Supérieur des Sciences Appliquées et Technologie, Université de Monastir, Avenue El Mourouj, 5111, Mahdia, Tunisia

    Sana Chaalia & Amor Haddad

  2. Laboratoire de Chimie de Coordination (LCC), CNRS-Université de Toulouse, 205, Route de Narbonne, 1077, Toulouse, France

    Jean-Claude Daran

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  1. Sana Chaalia
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  2. Jean-Claude Daran
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  3. Amor Haddad
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Correspondence to Sana Chaalia.

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Chaalia, S., Daran, JC. & Haddad, A. A New Organic-Paradodecatungstate Hybrid Compound: Synthesis, Characterization and Crystal Structure. J Clust Sci 24, 851–864 (2013). https://doi.org/10.1007/s10876-013-0582-3

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