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New BPTH-Bridged Chained Cd(II) Coordination Polymer Based on Cd2O2 Clusters: Synthesis and Crystal Structure of [Cd(BPTH)(phen)]·3.75H2O (BPTH = biphthalhydrazidate; phen = phenanthroline)

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Abstract

Based on the hydrothermal in situ acylation reaction of 4,4′-biphthalic acid (bpha) with N2H4·H2O, a new acylhydrazidate-bridged 1-D chained Cd2+ coordination polymer [Cd(BPTH)(phen)]·3.75H2O (BPTH = 4,4′-biphthalhydrazidate, phen = phenanthroline) was synthesized, and characterized by elemental analysis, infrared spectroscopy, powder X-ray diffraction (XRD), thermogravimetric analysis and single-crystal XRD. With ancillary phen molecules, the BPTH molecules link the Cd2+ centers into a 1-D staircase chain structure of compound 1 based on the Cd2O2 clusters.

Graphical Abstract

Based on the hydrothermal in situ acylation reaction of 4,4′-biphthalic acid (bpha) with N2H4·H2O, a new acylhydrazidate-bridged 1-D chained Cd2+ coordination polymer [Cd(BPTH)(phen)]·3.75H2O (BPTH = 4,4′-biphthalhydrazidate, phen = phenanthroline) was synthesized. With ancillary phen molecules, the BPTH molecules link the Cd2+ centers into a 1-D staircase chain structure of compound 1 based on the Cd2O2 clusters.

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References

  1. X. M. Chen and M. L. Tong (2007). Acc. Chem. Res. 40, 162.

    Article  Google Scholar 

  2. X. M. Zhang (2005). Coord. Chem. Rev. 249, 1201.

    Article  CAS  Google Scholar 

  3. H. Zhao, Z. R. Qü, H. Y. Ye, and R. G. Xiong (2008). Chem. Soc. Rev. 37, 84.

    Article  Google Scholar 

  4. J. Jin, F. Q. Bai, M. J. Jia, Y. Peng, J. H. Yu, and J. Q. Xu (2011). Dalton Trans. (accepted).

  5. J. H. Yu, Y. C. Zhu, D. Wu, Y. Yu, Q. Hou, and J. Q. Xu (2009). Dalton Trans. 8248.

  6. J. Jin, W. Xu, M. J. Jia, J. J. Zhao, J. H. Yu, and J. Q. Xu (2011). Inorg. Chim. Acta 378, 72.

    Article  CAS  Google Scholar 

  7. J. Jin, J. M. Jia, F. Q. Bai, Y. Peng, J. H. Yu, and J. Q. Xu (2011). Dalton Trans. (submitted).

  8. J. Jin, D. Wu, J. M. Jia, Y. Peng, J. H. Yu, Y. C. Wang, and J. Q. Xu (2011). J. Solid State Chem. 184, 667.

    Article  CAS  Google Scholar 

  9. J. Jin, M. J. Jia, Y. Peng, Q. Hou, J. H. Yu, and J. Q. Xu (2010). CrystEngComm 12, 1850.

    Article  CAS  Google Scholar 

  10. J. H. Yu, J. Q. Xu, L. Ye, H. Ding, W. J. Jing, T. G. Wang, J. N. Xu, H. B. Jia, Z. C. Mu, and G. D. Yang (2002). Inorg. Chem. Commun. 5, 572.

    Article  CAS  Google Scholar 

  11. Q. Hou, X. J. Qu, J. Jin, J. J. Zhao, J. H. Yu, and J. Q. Xu (2011). J. Clust. Sci. 22, 715.

    Article  CAS  Google Scholar 

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Acknowledgments

This research was supported by the basic research foundation of Jilin University (No. 200903133) and a branch of cooperation project (No. 3R111N651412).

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Authors and Affiliations

  1. College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130023, Jilin, People’s Republic of China

    Juan Jin, Jin-Jing Zhao, Jie-Hui Yu & Ji-Qing Xu

  2. Key Laboratory of Surface and Interface Chemistry of Jilin Province, College of Chemistry, Jilin University, Qianjin Road 2699, Changchun, 130012, Jilin, People’s Republic of China

    Ming-Jun Jia

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  1. Juan Jin
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  2. Ming-Jun Jia
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  3. Jin-Jing Zhao
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  4. Jie-Hui Yu
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  5. Ji-Qing Xu
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Correspondence to Jie-Hui Yu or Ji-Qing Xu.

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Jin, J., Jia, MJ., Zhao, JJ. et al. New BPTH-Bridged Chained Cd(II) Coordination Polymer Based on Cd2O2 Clusters: Synthesis and Crystal Structure of [Cd(BPTH)(phen)]·3.75H2O (BPTH = biphthalhydrazidate; phen = phenanthroline). J Clust Sci 23, 287–295 (2012). https://doi.org/10.1007/s10876-011-0428-9

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  • DOI: https://doi.org/10.1007/s10876-011-0428-9

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