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Self-Assembly of Isopolyanion Clusters and Lanthanide-Organic Units into 2D Layers: (NH4)2{[Ln2(C7H4NO4)2(H2O)9][(H2W12O40)]}·nH2O (Ln = Gd, Tb, Ho)

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Abstract

Three novel 1:2 composite compounds prepared with the isopolyanions and lanthanide-organic units, (NH4)2{[Ln2(HL)2(H2O)9][(H2W12O40)]}·nH2O (Ln = Gd3+ (1), Tb3+ (2), n = 15; Ho3+ (3), n = 10; L = pyridine-3,5-dicarboxylate) were synthesized at room temperature and characterized by routine methods. X-ray structural analysis reveals that these structures are isomorphic: two crystallographically independent Ln3+ ions (Ln1 and Ln2) locate in different coordination environments; two ligands plays dissimilar coordination mode; the isopolyanion cluster acts as a tridentate ligand and connects three Ln3+ ions (Ln1, Ln1′ and Ln2) forming an unusual 2D undee-layer. The room temperature luminescent of 2 has been studied and exhibits a Tb3+ characteristic emission in the range of 450–650 nm.

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  1. Department of Chemistry, Baicheng Normal College, Baicheng, 137000, People’s Republic of China

    Zheyu Zhang

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  1. Zheyu Zhang
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Correspondence to Zheyu Zhang.

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Zhang, Z. Self-Assembly of Isopolyanion Clusters and Lanthanide-Organic Units into 2D Layers: (NH4)2{[Ln2(C7H4NO4)2(H2O)9][(H2W12O40)]}·nH2O (Ln = Gd, Tb, Ho). J Clust Sci 22, 705–714 (2011). https://doi.org/10.1007/s10876-011-0416-0

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  • DOI: https://doi.org/10.1007/s10876-011-0416-0

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