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1,ω-Bis(pyridinium)alkane Cation as Templates for the Self-Assembly of the Mo(W)/S/Cu Polymeric Clusters

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Abstract

Self-assembly of a series of effective cation-templates with [Mo(W)/Cu/S]-based clusters was studied. Permanent templated products {(bppp)[MoOS3Cu3I3(4,4′-bipy)1.5]}n (1), {(bpbt)[MoOS3Cu3I3(4,4′-bipy)1.5]}n (2), {(bppp)[WOS3Cu3I3(4,4′-bipy)1.5]}n (3), and {(bpbt)[WOS3Cu3Br3(4,4′-bipy)1.5]}n (4) show 1D anionic zigzag pattern (bppp = 1,3-bis(pyridinium) propane, bpbt = 1,4-bis(pyridinium) butane). Compounds 1–4 have been characterized by single-crystal X-ray diffraction, elemental analysis, IR, UV–vis and thermogravimetric Analysis. The results may provide fascinating insights into template effects on the construction of the cluster-based coordination polymers and that coordination modes of compounds 3 and 4 have not been found in the reported one-dimensional zigzag coordination polymers.

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Authors and Affiliations

  1. Department of Chemistry, Zhengzhou University, Zhengzhou, 450001, People’s Republic of China

    Hong-Mei Wang, Zhen-Hua Zhang, Yun-Yin Niu & Ben-Lai Wu

  2. College of Chemistry and Chemical Engineering, Xinxiang University, Xinxiang, 453000, People’s Republic of China

    Yu Liang

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  1. Hong-Mei Wang
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  2. Yu Liang
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  4. Yun-Yin Niu
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Correspondence to Yu Liang or Yun-Yin Niu.

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Wang, HM., Liang, Y., Zhang, ZH. et al. 1,ω-Bis(pyridinium)alkane Cation as Templates for the Self-Assembly of the Mo(W)/S/Cu Polymeric Clusters. J Clust Sci 22, 633–646 (2011). https://doi.org/10.1007/s10876-011-0404-4

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