Skip to main content
SpringerLink
Log in

Unique (3,12)-Connected Inorganic Lanthanide Cluster Polymer Based on Octahedral Hexanuclear Europium Hydroxide Clusters and Sulfate Anions: Synthesis, Structure, and Luminescence

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

A (3,12)-connected 3D inorganic luminescent lanthanide hydroxide cluster polymer [Eu6(μ6-O) (μ3-OH)8(H2O)6(SO4)4] n (1) has been hydrothermally synthesized and characterized. The structure can be considered to be constructed by linking 12-connected octahedral hexanuclear lanthanide oxido/hydroxide clusters with 3-connected inorganic SO4 2− anions. Presently, it is the first 3D inorganic lanthanide cluster polymer based on octahedral hexanuclear lanthanide cluster with the highest connected binodal network topology. 1 displays red luminescent emission and exhibits the characteristic transitions of the Eu3+ ion with a decay lifetime of 196.25 μs in the solid state at room temperature.

Graphical Abstract

.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. R. Y. Wang, H. D. Selby, H. Liu, M. D. Carducci, T. Z. Jin, Z. P. Zheng, J. W. Anthis, and R. J. Staples (2002). Inorg. Chem. 41, 278.

    Article  CAS  Google Scholar 

  2. Z. P. Zheng (2001). Chem. Commun. 2521.

  3. M. Addamo, G. Bombieri, E. Foresti, M. D. Grillone, and M. Volpe (2004). Inorg. Chem. 43, 1603.

    Article  CAS  Google Scholar 

  4. A. V. Mudring, T. Timofte, and A. Babai (2006). Inorg. Chem. 45, 5162.

    Article  CAS  Google Scholar 

  5. X. J. Kong, L. S. Long, L. S. Zheng, R. Y. Wang, and Z. P. Zheng (2009). Inorg. Chem. 48, 3268.

    Article  CAS  Google Scholar 

  6. L. Huang, L. Han, W. Feng, L. Zheng, Z. Zhang, Y. Xu, Q. Chen, D. Zhu, and S. Niu (2010). Cryst. Growth Des. 10, 2548.

    Article  CAS  Google Scholar 

  7. F. Gándara, E. Gutiérrez-Puebla, M. Iglesias, N. Snejko, and M. A. N. Monge (2010). Cryst. Growth Des. 10, 128.

    Article  Google Scholar 

  8. A. Kornienko, T. J. Emge, G. A. Kumar, R. E. Riman, and J. G. Brennan (2005). J. Am. Chem. Soc. 127, 3501.

    Article  CAS  Google Scholar 

  9. L. Z. Zhang, W. Gu, B. Li, X. Liu, and D. Z. Liao (2007). Inorg. Chem. 46, 622.

    Article  CAS  Google Scholar 

  10. Y. B. Dong, P. Wang, J. P. Ma, X. X. Zhao, H. Y. Wang, B. Tang, and R. Q. Huang (2007). J. Am. Chem. Soc. 129, 4872.

    Article  CAS  Google Scholar 

  11. K. Manseki and S. Yanagida (2007). Chem. Commun. 1242.

  12. T. Kajiwara, K. Katagiri, M. Hasegawa, A. Ishii, M. Ferbinteanu, S. Takaishi, T. Ito, M. Yamashita, and N. Iki (2006). Inorg. Chem. 45, 4880.

    Article  CAS  Google Scholar 

  13. R. Y. Wang, H. Liu, M. D. Carducci, T. Z. Jin, C. Zheng, and Z. P. Zheng (2001). Inorg. Chem. 40, 2743.

    Article  CAS  Google Scholar 

  14. G. Xu, Z. M. Wang, Z. He, Z. Lu, C. S. Liao, and C. H. Yan (2002). Inorg. Chem. 41, 6802.

    Article  CAS  Google Scholar 

  15. R. Y. Wang, Z. P. Zheng, T. Z. Jin, and R. J. Staples (1999). Angew. Chem. Int. Ed. 38, 1813.

    Article  CAS  Google Scholar 

  16. R. Anwander (1998). Angew. Chem. Int. Ed. 37, 599.

    Article  CAS  Google Scholar 

  17. X. Li, H. L. Sun, X. S. Wu, X. Qiu, and M. Du (2010). Inorg. Chem. 49, 1865.

    Article  CAS  Google Scholar 

  18. W. Q. Fan, J. Feng, S. Y. Song, Y. Q. Lei, G. L. Zheng, and H. J. Zhang (2010). Chem. Eur. J. 16, 1903.

    Article  CAS  Google Scholar 

  19. J. W. Cheng, J. Zhang, S. T. Zheng, M. B. Zhang, and G. Y. Yang (2006). Angew. Chem. Int. Ed. 45, 73.

    Article  CAS  Google Scholar 

  20. N. Mahe, O. Guillou, C. Daiguebonne, Y. Gerault, A. Caneschi, C. Sangregorio, J. Y. Chane-Ching, P. E. Car, and T. Roisnel (2005). Inorg. Chem. 44, 7743.

    Article  CAS  Google Scholar 

  21. C. M. Zaleski, E. C. Depperman, J. W. Kampf, M. L. Kirk, and V. L. Pecoraro (2004). Angew. Chem. Int. Ed. 43, 3912.

    Article  CAS  Google Scholar 

  22. S. C. Xiang, S. M. Hu, T. L. Sheng, R. B. Fu, X. T. Wu, and X. D. Zhang (2007). J. Am. Chem. Soc. 129, 15144.

    Article  CAS  Google Scholar 

  23. X. J. Kong, Y. P. Ren, L. S. Long, Z. P. Zheng, G. Nichol, R. B. Huang, and L. S. Zheng (2008). Inorg. Chem. 47, 2728.

    Article  CAS  Google Scholar 

  24. Y. G. Huang, F. L. Jiang, and M. C. Hong (2009). Coord. Chem. Rev. 253, 2814.

    Article  CAS  Google Scholar 

  25. A. Zulys, T. K. Panda, M. T. Gamer, and P.W. Roesky (2004). Chem. Commun. 2584.

  26. M. R. Burgstein and P. W. Roesky (2000). Angew. Chem. Int. Ed. 39, 549.

    Article  CAS  Google Scholar 

  27. Z. Zak, P. Unfried, and G. Giester (1994). J. Alloys. Compd. 205, 235.

    Article  CAS  Google Scholar 

  28. G. Giester, P. Unfried, and Z. Zak (1997). J. Alloys. Compd. 257, 175.

    Article  CAS  Google Scholar 

  29. O. Guillou, C. Daiguebonne, G. Calvez, F. Le Dret, and P. E. Car (2008). J. Alloys. Compd. 451, 329.

    Article  CAS  Google Scholar 

  30. G. Calvez, O. Guillou, C. Daiguebonne, P. E. Car, V. Guillerm, Y. Gerault, F. Le Dret, and N. Mahe (2008). Inorg. Chim. Acta 361, 2349.

    Article  CAS  Google Scholar 

  31. Z. C. Zhang (2008). Acta. Crystallogr. C. 64, M381.

    Article  Google Scholar 

  32. S. Q. Ma, D. Q. Yuan, X. S. Wang, and H. C. Zhou (2009). Inorg. Chem. 48, 2072.

    Article  CAS  Google Scholar 

  33. Y. Q. Sun, J. Zhang, and G. Y. Yang (2006). Chem. Commun. 1947.

  34. G. M. Sheldrick SHELXS-97, Program for Crystal Structure Solution (University of Göttingen, Göttingen, 1997).

    Google Scholar 

  35. G. M. Sheldrick SHELXS-97, Program for Crystal Structure Refinement (University of Göttingen, Göttingen, 1997).

    Google Scholar 

  36. M. J. Hardie, C. L. Raston, and A. Salinas (2001). Chem. Commun. 1850.

  37. L. Hou, J. P. Zhang, X. M. Chen, and S. W. Ng (2008). Chem. Commun. 4019.

  38. L. Hou, W. X. Zhang, J. P. Zhang, W. Xue, Y. B. Zhang, and X. M. Chen (2010). Chem. Commun. 46, 6311.

    Article  CAS  Google Scholar 

  39. Y. Q. Lan, S. L. Li, K. Z. Shao, X. L. Wang, D. Y. Du, Z. M. Su, and D. J. Wang (2008). Cryst. Growth Des. 8, 3490.

    Article  CAS  Google Scholar 

  40. K. Sumida, M. R. Hill, S. Horike, A. Dailly, and J. R. Long (2009). J. Am. Chem. Soc. 131, 15120.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This research study was supported by the NNSF of China (No. 21003020), the Doctoral Fund of Ministry of Education of China (No. 20093514120002), the Innovation Fund for Young Scientist of Fujian Province (No. 2008F3120), Program for New Century Excellent Talents of Fujian Province (Grant SXSJRC2007-21), the Special Foundation for Young Scientists of Fuzhou University (Grant XRC-0840).

Author information

Authors and Affiliations

  1. Department of Chemistry, Fuzhou University, Fuzhou, 350108, People’s Republic of China

    Yan-Qiong Sun, Hong-Xin Mei, Han-Hui Zhang, Yi-Ping Chen & Rui-Qing Sun

Authors
  1. Yan-Qiong Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hong-Xin Mei
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Han-Hui Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yi-Ping Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Rui-Qing Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Yan-Qiong Sun or Han-Hui Zhang.

Electronic supplementary material

Below is the link to the electronic supplementary material.

10876_2011_380_MOESM1_ESM.doc

Crystal structure data of 1 can be obtained from Fachinformationszentrum Karlsruhe FIZ, 76344 Eggenstein-Leopoldshafen, Germany (fax: + 497247808666; crysdata@fiz.karlsruhe.de) under depository number:CSD-422566 (DOC 5712 kb).

Rights and permissions

Reprints and permissions

About this article

Cite this article

Sun, YQ., Mei, HX., Zhang, HH. et al. Unique (3,12)-Connected Inorganic Lanthanide Cluster Polymer Based on Octahedral Hexanuclear Europium Hydroxide Clusters and Sulfate Anions: Synthesis, Structure, and Luminescence. J Clust Sci 22, 279–288 (2011). https://doi.org/10.1007/s10876-011-0380-8

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-011-0380-8

Keywords

Search

Navigation