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Trinuclear Metal Cluster Complexes Containing Fischer-Type Carbene Group from Oxidative Addition Reactions of Tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12

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Abstract

Two new Fischer-type carbene-containing trinuclear transition-metal clusters: (μ 3-S)Co3(CO)7[μ, η 2-SCNEt2] 1 and CoRu2(CO)9[μ 3, η 2-SCNEt2] 2 were obtained by the reaction of tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12. These clusters contain thiocarboxamido ligand in different coordination modes. The thiocarboxamido ligand served as monometalated or dimetalated sulfur(diethy1amino) carbene ligand in these clusters. Clusters 1 and 2 were characterized by IR, 1H NMR, and single-crystal X-ray diffraction.

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Acknowledgement

The authors acknowledge the support of this work by the National Science Fund for Distinguished Young Scholars of China (No. 20625308).

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Authors and Affiliations

  1. State key laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, People’s Republic of China

    Jing-Mu Yang, Bin Hu & Chun-Gu Xia

  2. Graduate School of Chinese Academy of Sciences, Beijing, 100039, People’s Republic of China

    Jing-Mu Yang

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  1. Jing-Mu Yang
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  2. Bin Hu
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Correspondence to Chun-Gu Xia.

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Yang, JM., Hu, B. & Xia, CG. Trinuclear Metal Cluster Complexes Containing Fischer-Type Carbene Group from Oxidative Addition Reactions of Tris(N,N-diethyldithiocarbamato)cobalt with Co2(CO)8 and Ru3(CO)12 . J Clust Sci 19, 615–621 (2008). https://doi.org/10.1007/s10876-008-0201-x

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  • DOI: https://doi.org/10.1007/s10876-008-0201-x

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