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Hydrothermal Synthesis and Structures of Two One-Dimensional Heteropolytungstates Chains Formed by Keggin Cluster Units

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Abstract

Single crystals of [W11Ni1P1O39(Hbpy)](H2bpy)2 · 4.25H2O (1) and (W11Zn1P1O39)(H2bpy)2(Hbpy) · 1.5H2O (2) have been hydrothermally synthesized at 160 °C and both characterized by IR, elemental and single-crystal structural analyses. Compound 1 has a ladder-like chain structure by hydrogen bonding interactions, whereas 2 contains an unprecedented chain of Keggin polyoxotungstates by oxo-bridges and form a 2-D layer via hydrogen bonds.

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Acknowledgments

This work was supported by the grants of 973 Program (2006CB932900), National Nature Science Foundation of China, NSF for Young Scientists of China (20801056) and Nature Science Foundation of Fujian Province, Young Scientist Funds of Fujian Province (No. 2007F3111).

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Authors and Affiliations

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, People’s Republic of China

    Lian Chen, Fei-Long Jiang, Ning Li, Wen-Tao Xu & Mao-Chun Hong

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  1. Lian Chen
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  2. Fei-Long Jiang
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  3. Ning Li
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  4. Wen-Tao Xu
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Correspondence to Fei-Long Jiang.

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Chen, L., Jiang, FL., Li, N. et al. Hydrothermal Synthesis and Structures of Two One-Dimensional Heteropolytungstates Chains Formed by Keggin Cluster Units. J Clust Sci 19, 591–600 (2008). https://doi.org/10.1007/s10876-008-0199-0

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