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A Novel 3D Platinum–Thallium Coordination Polymer having Strong Metal–Metal Interactions

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Abstract

A new three-dimensional platinum(II)–thallium(I) coordination polymer [{Pt(pda)(NHCOtBu)2}4Tl4][Pt(CN)4]2·2H 2 O (pda = 1,2-propyldiamine) has been prepared from the direct reaction of [Tl2Pt(CN)4] and [Pt(pda)(NHCOtBu)2] in water, and its structure was characterized by X-ray diffraction analysis. The compound crystallizes in monoclinic, space group Pn, a = 11.567(2) Å, b = 11.570(2) Å, c = 37.677(8)Å, β = 94.64(3)°, V = 5025.8(17) Å3, Z = 2, R1 = 0.0679 and wR2 = 0.1574 [I >  2σ (I)], Goodness-of-fit on F 2 = 1.055. The compound exhibits a novel 3D network structure consisting of [Pt(CN)4]2− connected 1D infinite Pt–Tl–Pt–Tl chains via strong Pt–Tl bonds.

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Acknowledgements

G. W. thanks Zhejiang Provincial Natural Science Foundation for the financial support of this work.

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Authors and Affiliations

  1. Department of Chemical Engineering, West Branch of Zhejiang University of Technology, Quzhou, 324000, China

    Guoqiang Wu

  2. Department of Chemistry, Liaocheng University, Liaocheng, 252059, China

    Daqi Wang

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  1. Guoqiang Wu
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  2. Daqi Wang
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Correspondence to Guoqiang Wu.

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Wu, G., Wang, D. A Novel 3D Platinum–Thallium Coordination Polymer having Strong Metal–Metal Interactions. J Clust Sci 18, 406–413 (2007). https://doi.org/10.1007/s10876-007-0115-z

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