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Novel Organically Templated 2-D Silver(I)-Iodide Coordination Architecture: Syntheses and Characterization

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A new two-dimensional silver(I)-iodide coordination architecture [(dbp · H2)1.5(Ag6I9)] n (1) (dbp = N,N′-dibutyl-piperazine) templated by appropriate cation has been constructed and structurally, thermally and optically characterized. The compound crystallizes in monoclinic, space group P2(1)/n, a = 12.198(2) Å, b = 14.464(3) Å, c =  28.108(6) Å, β =  91.69(3)°, V = 4957.0(17) Å3, Z = 4, R 1 = 0.0576 and wR 2 = 0.1794[I  >  2σ(I)]. The inorganic moiety of 1 presents two-dimensional arrangement that results from the apexes and edges-sharing of AgI4 tetrahedrons. Electrostatic interactions between organic countercations and inorganic layers are presented and contribute to the crystal packing. Optical limiting measurement indicates that 1 possesses optical limiting activity.

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Acknowledgments

We acknowledge support of this research by the Foundation of Education Committee of Fujian Province (JB04016 and JB04017).

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  1. Center of Analysis and Measurement, Fuzhou University, Fuzhou, Fujian, 350002, P. R. China

    Xiao Guang-Can

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  1. Xiao Guang-Can
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Guang-Can, X. Novel Organically Templated 2-D Silver(I)-Iodide Coordination Architecture: Syntheses and Characterization. J Clust Sci 17, 457–466 (2006). https://doi.org/10.1007/s10876-006-0069-6

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  • DOI: https://doi.org/10.1007/s10876-006-0069-6

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