Skip to main content
Log in

Precipitation Chemistry and Wet Deposition in Kruger National Park, South Africa

  • Published:
Journal of Atmospheric Chemistry Aims and scope Submit manuscript

Abstract

The chemical composition, as well as the sources contributing to rainwater chemistry have been determined at Skukuza, in the Kruger National Park, South Africa. Major inorganic and organic ions were determined in 93 rainwater samples collected using an automated wet-only sampler from July 1999 to June 2002. The results indicate that the rain is acidic and the averaged precipitation pH was 4.72. This acidity results from a mixture of mineral acids (82%, of which 50% is H2SO4) and organic acids (18%). Most of the H2SO4 component can be attributed to the emissions of sulphur dioxide from the industrial region on the Highveld. The wet deposition of S and N is 5.9 kgS⋅ha−1⋅yr−1 and 2.8 kgN⋅ha−1⋅yr−1, respectively. The N deposition was mainly in the form of NH4 +. Terrigenous, sea salt component, nitrogenous and anthropogenic pollutants have been identified as potential sources of chemical components in rainwater. The results are compared to observations from other African regions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Andreae, M. O., Andreae, R. W., Berresheim, H. and Beecher, K. M., 1990: Precipitation chemistry in central Amazonia, J. Geophys. Res. 95, 16,987–17,000.

    Google Scholar 

  • Annegarn, H. J., Kneen, M. A., Piketh, S. J., Horne, A. R., Hlapolosa, H. P. S., and G. A. Kirkman, G. A., 1993: Evidence of large-scale circulation of anthropogenic sulphur over southern Africa, in Proceedings of the 24th National Association for Clean Air Conference, Clean Air Challenges in a changing South Africa, Brits.

  • Ayers, G. P. and Gillett, R. W., 1988: Acidification in Australia, in Acidification in Tropical Countries, edited by H. Rodhe, and R. Herrera, pp. 347–402, John Wiley, New York.

    Google Scholar 

  • Ayers, G. P., Peng, L. C., Fook, Kong, C. W., Gillett, R. W., and Manins, P. C., 2000: Atmospheric concentrations and deposition of oxidised sulphur and nitrogen species at Petaling Jaya, Malaysia, 1993–1998, Tellus B52, 60–73.

    Google Scholar 

  • Blanchard, D. C., 1983: Air-Sea Exchange of Gases and Particles, NATO ASI Ser, Norwell, pp. 407–454.

  • Brocard, D., Lacaux, C., Lacaux, J. P., Kouadio, G., and Yoboué, V., 1996: Emissions from the combustion of biofuels in western Africa. In: J.S. Levine (Editor), Global Biomass Burning. MIT Press, Cambridge.

    Google Scholar 

  • Cosijn, C. and Tyson, P. D., 1996: Stable discontinuities in the atmosphere over South Africa, S. Afr. J. Sci. 92, 381–386.

    Google Scholar 

  • D'Abreton, P. and Tyson, P. D., 1996: Divergent and non-divergent water vapour transport over southern Africa during wet and dry conditions, Meteorol. Atmos. Phys. 55, 47–59.

    Article  Google Scholar 

  • Delmas, R., Loudjani, P., Podaire, A. and Menaut, J. C., 1991: Biomass burning in Africa: An assessment of annually burnt biomass, in J. S. Levine (ed.), Global Biomass Burning: Atmospheric, Climatic and Biospheric Implications, MIT Press, Cambridge, Massachusetts, pp. 126–133.

    Google Scholar 

  • EPA, 1994: Quality Assurance Handbook for Air Pollution Measurement Systems, EPA/600R-94/038e, United States Environmental Protection Agency, Office of Research and Development, Washington.

    Google Scholar 

  • Rocha, F. R., Jose, A. F., Claudimir, L. L., Adalgiza, F., and Ivano, G. R. G., 2003: Wet deposition and related atmospheric chemistry in the Sao Paulo metropolis, Brazil:Part 1. Major inorganic ions in rainwater as evaluated by capillary electrophoresis with contactless conductivity detection, Atmos. Environ. 37, 105–115.

    Article  Google Scholar 

  • Furiness, C., Smith, L., Ran, L. and Cowling, E., 1998: Comparison of emissions of Nitrogen and sulphur oxides to deposition of nitrate and sulphate in the USA by state in 1990, Environmental Pollution 102, 313–320.

    Article  Google Scholar 

  • Galloway, J. N., Andreae, M. O., Talbot, R. W., Andreae, T. W. and Hariss, R. C., 1988: Formic and acetic acid over the central Amazon region, Brazil, 1, Dry season, J. Geophys. Res. 93, 1616–1624.

    Google Scholar 

  • Galy-Lacaux, C. and Modi, A. I., 1998: Precipitation chemistry in the Sahelian Savanna, J. Atmos. Chem. 30, 319–343.

    Article  Google Scholar 

  • Galy-Lacaux, C., Carmichael, G. R., Song, C. H., Lacaux, J. P., and Modi, A. I., 2001: Heterogeneous processes involving nitrogenous compounds and Saharan dust inferred from measurements and model calculations Region, J. Geophys. Res. 106, 12559–12578.

    Article  Google Scholar 

  • Gillett, R. W., Ayers, G. P., Mhwe, T., Selleck, P. W. and Harjanto, H., 2000: Concentration of nitrogen and sulfur species in gas and rainwater from several sites in Indonesia, Water, Air and Soil Pollution 120, 205–215.

    Article  Google Scholar 

  • Gong, S. L., Barrie, L. A. and Blanchet, J. P., 1997: Modeling sea-salt aerosols in the atmosphere, I, Model development, J. Geophys. Res. 102, 3805–3818.

    Article  Google Scholar 

  • Held, G., Scheifinger, H. and Snyman, G. M., 1994: Recirculation of pollutants in the Atmosphere of the South African Highveld, S. Afr. J. Sci. 90, 91–97.

    Google Scholar 

  • IPCC., 2001: The Regional Impacts of Climate Change: An assessment of Vulnerability, Cambridge Univ. Press, New York.

    Google Scholar 

  • Keene, W. C., Pszenny, A. A. P., Galloway, J. N., and Hartley, M. E., 1986: Sea-salt corrections and interpretation of constituents ratios in marine precipitation, J. Geophys. Res. 91, 6647–6658.

    Article  Google Scholar 

  • Lacaux, J. P., Delmas, R., Kouadio, G., Cros, B., and Andreae, M. O., 1992: Precipitation chemistry in the Moyombe forest of equatorial Africa, J. Geophys. Res. 97, 6195–6206.

    Google Scholar 

  • Lacaux, J. P., Servant, J. J. Huertas, M. L. Cros, B., and Delmas, R., 1988: Precipitation chemistry from remote sites in African equatorial forest, Eos Trans. AGU 69, 1069.

    Google Scholar 

  • Lacaux, J. P., Servant, J. J. and Baudet, J. G. R., 1987: Acid rain in the tropical forest of the Ivory Coast, Atmos. Environ. 21, 2643–2647.

    Article  Google Scholar 

  • Lacaux, J. P., Delmas, R., Cros, B., and Andreae, M. O., 1991: Influence of biomass burning emissions on precipitation chemistry in the equatorial forest of Africa, in Global Biomass Burning, edited by J. S. Levine, MIT, Cambridge.

    Google Scholar 

  • Lara, L. B. L. S., Artaxo, P., Martinelli, R. L., Victoria, R. L., Camargo, P. B., Krusche, A., Ayers, G. P., Ferraz, E. S. B. and Ballester, M. V., 2001: Chemical composition of rainwater and anthropogenic influences in the Piracicaba River Basin, Southeast Brazil, Atmos. Environ. 35, 4937–4945.

    Article  Google Scholar 

  • Lesack, L. F. W. and J. Melack, M, 1991: The deposition, composition and potential sources of major ionic solutes in rain of the Central Amazon Basin, Water Resources Research 27, 2953–2977.

    Article  Google Scholar 

  • Likens, G. E., Keene, W. C. Miller, J. M., and Galloway, J. N., 1987: Chemistry of precipitation from a remote terrestrial site in Australia, J. Geophys. Res. 92, 13,299–13,314.

    Article  Google Scholar 

  • Maenhaut, W., Cafmeyer, J., Rajta, I., Annegarn, H. J., and M. O. Andreae, M. O., 1996: Regional atmospheric aerosol composition and sources in the eastern Transvaal, South Africa, and impact of biomass burning, J. Geophys. Res. 101, 23631–23650.

  • Mamane, Y. and Gottlieb, J., 1995: Ten years of precipitation chemistry in Haifa, Israel, Water, Air and Soil Pollution 82, 548–558.

    Article  Google Scholar 

  • Mphepya, J. N., Pienaar, J. J., Galy-Lacaux, C., Held, G., and Turner, C. R., 2004: Precipitation Chemistry in semi-arid Areas of Southern Africa: A case Study of a rural and an Industrial site., J. Atmos. Chem. 47, 1–24.

    Article  Google Scholar 

  • Munger, J. W. and Eisenreich, S. J., 1983: Continental-scale variations in precipitations in precipitation chemistry, Environmetal Science and Technology 17, 32–42.

    Article  Google Scholar 

  • Otter, L. B., Marufu, L. and Scholes, M. C., 2001: Biogenic, biomass and biofuel sources of trace gases in southern Africa, S. Afr. J. Sci. 97, 131–138.

    Google Scholar 

  • Piketh, S., Annegarn, H. J. and Tyson, P. D., 1999: Lower-tropospheric loading over South Africa: the relative contributions of aeolian dust, industrial emissions and biomass burning, J. Geophys. Res. 104, 1597–1607.

    Article  Google Scholar 

  • Pszenny, A. A. P., Keene, W. C., O'Dowd, C., Smith, M., and Quinn, P., 1998: Sea salt aerosols, tropospheric sulphur cycling and climate forcing, in Global Change News.

  • Puxbaum, H., Simeonov, V. and Kalina, M. F., 1998: Ten years trends (1984–1993) in the precipitation chemistry in central Austria, Atmos. Environ. 32, 193–202.

    Article  Google Scholar 

  • Roberts, C. G., Andreae, M. O., Maenhaut, W. and Fernandez-Jimenez, M. T., 2001: Composition and sources of aerosols in a central Africa rain forest during the dry season, J. Geophys. Res. 106, 14, 423–14, 434.

    Google Scholar 

  • Sanhueza, E., Arias, M. C., Donoso, L., Graterol, N., Hermoso, M., Marti, I., Romero, J., 1992: Chemical composition of acid rains in the Venezuelan savannah region, Tellus 44B, 54–62.

    Google Scholar 

  • Schlesinger, W. H. and Hartley, A. E., 1992: A global budget for atmospheric NH3, Biogeochemistry 15, 191–211.

    Article  Google Scholar 

  • Scholes, R. J. and Walker, B. H., 1993: An African Savanna, in Synthesis of the Nylsvely study, Cambridge University Press, Cambridge, Massachusetts, 164–67.

    Google Scholar 

  • Schulze, B. R., 1965: Climate of South Africa, SA Weather Bureau, Department of Environment and Tourism, Pretoria.

    Google Scholar 

  • Sigha-Nkamdjou, L., Galy-Lacaux, C., Pont, V., Richard, S., Sighomnou, D., and Lacaux, J. P., 2003: Rainwater chemistry and wet deposition over the equatorial forested ecosystem of Zoetele (Cameroon), J. Atmos. Chem. 46, 173–198.

    Article  Google Scholar 

  • Swap, R. J. and Tyson, P. D., 1999: Stable discontinuities as determinants of the vertical distribution of aerosols and trace gases in the atmosphere, S. Afr. J. Sci. 95, 63–71.

    Google Scholar 

  • Turner, C. R., Wells, R. B., and Olbrich, K. A., 1996: Deposition chemistry in South Africa, in Air Pollution and Its mpacts on the South African Highveld, edited by G. Held, B. J. Gore, A. D. Surridge, G. R. Tosen, C. R, and R. D. Walmsley, Environmental Scientific Assocition, Cleveland, 80–85.

    Google Scholar 

  • Tyson, P. D., Garstang, M., Swap, R. J., Edwards, M., and Kallberg, P., 1996: An air transport climatology for subtropical southern Africa, International Journal of Climatology 16, 151–163.

    Article  Google Scholar 

  • Van der Walt, H., du Toit, P., Pienaar, J. J., and Julies, A., 1998: Integration of passive sampler monitoring in non-electrified residential areas into a modern ambient air quality monitoring network, Proceedings, 11th World Clean Air and Environment Congress, Durban, 13–18 September,2005

  • Venter, F. J. and Gertenbach, P. D., 1986: A cursory review of the climate and vegetation of the Kruger National Park, Koedoe 29, 139–148.

    Google Scholar 

  • Williams, M. R., Fischer, T. M., and Melack, J., 1997: Chemical composition and deposition of rain in Central Amazon, Brazil, Atmos. Environ. 31, 207–217.

    Article  Google Scholar 

  • Yoboué, V., 1991: Caractéristiques physiques et chimiques des aérosols et des pluies collectés dans la savane humide de Côte d'lvoire, PhD No.914 Thesis, Université Paul Sabatier de Toulouse, Toulouse, France.

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Mphepya, J.N., Galy-Lacaux, C., Lacaux, J.P. et al. Precipitation Chemistry and Wet Deposition in Kruger National Park, South Africa. J Atmos Chem 53, 169–183 (2006). https://doi.org/10.1007/s10874-005-9005-7

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10874-005-9005-7

Keywords

Navigation