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Two Novel 2D Zn (II) Coordination Polymers with Quinoline-3-Carboxylic Acid and Tetraphenylphthalic Acid: Synthesis and Photoluminescence Properties

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Abstract

Two novel two-dimensional (2D) Zn coordination polymers,namely [Zn(qnl)2]n (Zn-qnl) and [Zn2(tpp)(OH)2(H2O)]n (Zn-tpp) (qnl = quinoline-3-carboxylate anion, tpp = tetraphenyl phthalate anion) have been hydrothermally synthesized and discussed their solid state photoluminescent properties.

Graphical Abstract

Two novel Zn coordination polymers with ligands quinoline-3-carboxylic acid (Hqnl) and tetraphenylphthalic acid (H2tpp) have been prepared and characterized by X-ray crystallography. Zn-tpp and Zn-qnl show a 2D hinge layer and a 2D layer with quadrilateral meshes, respectively.

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Acknowledgements

This work was supported the Shandong Provincial Natural Science Foundation of China (Grant No. ZR2017MB051).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, University of Jinan, Jinan, 250022, People’s Republic of China

    Yang Shi & Qi-Bing Bo

  2. College of Chemistry and Material Engineering, Fuyang Normal University, Fuyang, 236037, People’s Republic of China

    Miao-Miao Song & Dong-Liang Tao

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  1. Yang Shi
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  2. Miao-Miao Song
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  3. Dong-Liang Tao
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Correspondence to Qi-Bing Bo.

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Shi, Y., Song, MM., Tao, DL. et al. Two Novel 2D Zn (II) Coordination Polymers with Quinoline-3-Carboxylic Acid and Tetraphenylphthalic Acid: Synthesis and Photoluminescence Properties. J Chem Crystallogr 50, 198–205 (2020). https://doi.org/10.1007/s10870-019-00790-9

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