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Synthesis, Crystal Structure and Luminescent Property of a Ternary Complex [Cd(sfdb)(3-pytpy)]2·2H2O (H2sfdb = 4,4′-Sulfonyldibenzoic Acid, 3-pytpy = 4′-(3-Pyridyl)-2,2′:6′,2″-Terpyridine)

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Abstract

A new ternary complex [Cd(sfdb)(3-pytpy)]2·2H2O (H2sfdb = 4,4′-Sulfonyldibenzoic acid, 3-pytpy = 4′-(3-pyridyl)-2,2′:6′,2″-terpyridine) 1 has been hydrothermally synthesized and characterized by the elemental analysis, IR spectroscopy and single crystal X-ray diffraction. X-ray diffraction analysis reveals that 1 (C34H24CdN4O7S) crystallizes in triclinic space group P-1, features an interesting 1D channel-containing supramolecular structure constructed from grid-like dimers via π–π stacking interactions. Unit cell parameters for 1: a = 8.866(2) Å, b = 11.083(3) Å, c = 15.790(4) Å, α = 103.612(4)°, β = 95.044(3)°, γ = 101.083(4)° and Z = 2. The luminescent spectrum shows the emission peak of complex 1 is at 392 nm which is attributed to the intraligand transition.

Graphical Abstract

A novel 1D channel-containing supramolecular structure [Cd(sfdb)(3-pytpy)]2·2H2O (H2sfdb = 4,4′-Sulfonyldibenzoic acid, 3-pytpy = 4′-(3-pyridyl)-2,2′:6′,2″-terpyridine) (1) was synthesized and characterized and the luminescent property of 1 was also investigated.

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Acknowledgement

This work was financially supported by the Special Fund for Basic Scientific Research of Central Colleges, Chang’an University (No. CHD2009JC022).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Chang’an University, Xi’an, 710061, Shaanxi, China

    Lei Gou

  2. College of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan’an, 716000, Shaanxi, China

    Xiao-Li Chen

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  1. Lei Gou
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Correspondence to Lei Gou.

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Gou, L., Chen, XL. Synthesis, Crystal Structure and Luminescent Property of a Ternary Complex [Cd(sfdb)(3-pytpy)]2·2H2O (H2sfdb = 4,4′-Sulfonyldibenzoic Acid, 3-pytpy = 4′-(3-Pyridyl)-2,2′:6′,2″-Terpyridine). J Chem Crystallogr 40, 859–862 (2010). https://doi.org/10.1007/s10870-010-9754-2

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  • DOI: https://doi.org/10.1007/s10870-010-9754-2

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