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The Solid State Structure of [TMEDAH2][B5O6(OH)4]2

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Abstract

The solid state structure of the pentaborate anion templated by a doubly protonated TMEDA cation is reported. The structure is typical of this family of ligands, featuring extensive hydrogen bonding. Spectroscopic characterisation is also reported.

Graphical Abstract

The structure of [TMEDAH2][B5O6(OH)4]2 is reported and hydrogen bonding gives a ‘brickwall’ type structure. This is a blue emitter in solution.

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Acknowledgements

FB thanks the Higher Education Commission of Pakistan for funding this work.

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Authors and Affiliations

  1. School of Chemistry, Trinity College, University of Dublin, Dublin 2, Ireland

    Farzana Begum, Brendan Twamley & Robert J. Baker

  2. Department of Chemistry, Mirpur University of Science and Technology, Mirpur, AJK, Pakistan

    Farzana Begum

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  1. Farzana Begum
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  2. Brendan Twamley
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  3. Robert J. Baker
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Correspondence to Robert J. Baker.

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Begum, F., Twamley, B. & Baker, R.J. The Solid State Structure of [TMEDAH2][B5O6(OH)4]2. J Chem Crystallogr 50, 171–175 (2020). https://doi.org/10.1007/s10870-019-00775-8

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  • DOI: https://doi.org/10.1007/s10870-019-00775-8

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