Abstract
A new 2D Cd(II) coordination polymer, {[Cd(4-cpa) (bpp)2H2O]·(4-cpa)·(H2O)} n (1) [4-cpa = 4-chlorophenoxyacetate, bpp = 1,3-bis(4-pyridyl)propane] has been hydrothermally synthesized and characterized by elemental analysis, IR-spectroscopy, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. Complex 1 consists of discrete 2D cadmium complex, 4-cpa counter ions and free water molecules, which are assembled into a 3D supramolecular structure through hydrogen bonds and π···π stacking interactions. Three-dimensional fluorescence spectra of 1 were detected at room temperature under the excitation and the emission wavelengths in the range of 300–600 nm with the interval of 5 nm. The lifetime of the excited state of 1 upon excitation of 443 nm in solid-state at room temperature is 30.21 ns. The 4-cpa ligand and complex 1 have been screened for their phytogrowth-inhibitory activities against Brassica campestris L. and Echinochloa utilis Ohwi et Yabuno, and the results are compared with the activity of sodium 2,4-dichlorophenoxyacetate.
Graphical Abstract
Hydrothermal synthesis of a new 2D Cd(II) coordination polymer, {[Cd(4-cpa) (bpp)2H2O]·(4-cpa)·(H2O)} n (1) [4-cpa = 4-chlorophenoxyacetate, bpp = 1,3-bis(4-pyridyl)propane] leading to a material that displays intense blue 3D luminescence properties and phytogrowth-inhibitory activities.
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References
Bradshaw D, Claridge JB, Cussen EJ, Prior TJ, Rosseinsky MJ (2005) Acc Chem Res 38:273
Deng H, Grunder S, Cordova, Valente C, Furukawa H, Hmadeh M, Gandara F, Whalley AC, Liu Z, Asahina S, Kazumori H, O’Keeffe M, Terasaki O, Stoddart JF, Yaghi OM (2012) Science 336:1018
Ma D, Li Y, Li Z (2011) Chem Commun 47:7377
Ma D, Wang W, Li Y, Li J, Daiguebonne C, Calvez G, Guillou O (2010) CrystEngComm 12:4372
Zacher D, Shekhah O, Woll C, Fischer RA (2009) Chem Soc Rev 38:1418
Du M, Li CP, Wu JM, Guo JH, Wang GC (2011) Chem Commun 47:8088
Zhang JP, Huang XC, Chen XM (2011) Chem Soc Rev 38:2385
Robin AY, Fromm KM (2006) Coord Chem Rev 250:2127
Ma D, Lu K, Guo H, Pan Y, Liu J (2012) J Mol Struct 1021:179
Yang EC, Chan YN, Liu H, Wang ZC, Zhao XJ (2009) Cryst Growth Des 9:4933
Ma DY, Lu K, Qin L, Guo HF, Peng XY, Liu JQ (2013) Inorg Chim Acta 396:84
Sun Y, Wang Z, Zhang H, Cao Y, Zhang S, Chen Y, Huang C, Yu X (2007) Inorg Chim Acta 360:2565
An J, Wang S, Yan B, Chen Z (2002) J Coord Chem 55:1223
Li C, Li DS, Zhao J, Mou YQ, Zou K, Xiao SZ, Du M (2011) CrystEngComm 13:6601
Cui Y, Yue Y, Qian G, Chen B (2012) Chem Rev 112:1126–1162
Liu HJ, Tao XT, Yang JX, Yan YX, Ren Y, Zhao HP, Xin Q, Yu WT, Jiang MH (2008) Cryst Growth Des 8:259–264
Qiu Y, Deng H, Mou J, Yang S, Zeller M, Batten SR, Wu H, Li J (2009) Chem Commun 5415–5417
Inamori Y, Nishiguchi K, Matsuo N, Tsujibo H, Baba K, Ishida N (1991) Chem Pharm Bull 39:2378
Bruker (2004) APEXII software, Version 6.3.1. Bruker AXS Inc., Madison
Sheldrick GM (2008) Acta Cryst A64:112
Spek AL (2005) PLATON, a multipurpose crystallographic tool. Utrecht University, Utrecht
Zhou JS, Cai J, Wang L, Ng SW (2004) Dalton Trans 1493
Vreshch VD, Lysenko AB, Chernega AN, Howard JAK, Krautscheid H, Sieler J, Domasevitch KV (2004) Dalton Trans 2899
Nakamoto K (1986) Infrared and Raman spectra of inorganic and coordination compounds, 4th edn. Wiley, New York
Liu B, Qiu QC, Peng G, Ma L, Jin LM, Cai JP, Deng H (2009) Inorg Chem Commun 12:1200
Offiong OE, Nfor E, Avi AA (2000) Transition Met Chem 25:369
Acknowledgments
This work was partially supported by Foundation for Distinguished Young Talents in Higher Education of Guangdong Province (2012LYM_0134), Science and Technology Planning Project of Zhaoqing City (2012G013), China Natural Science Fund (81202461), and the China Postdoctoral Science Foundation (2013M531906).
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Ma, DY., Guo, HF., Qin, L. et al. Construction of a New 2D Cadmium(II) Coordination Polymer Based on N- and O-Donor Ligands: Synthesis, Luminescence and Biological Activities. J Chem Crystallogr 44, 63–69 (2014). https://doi.org/10.1007/s10870-013-0484-0
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DOI: https://doi.org/10.1007/s10870-013-0484-0