Skip to main content
SpringerLink
Log in

Two Distinct Cu(I) Coordination Polymers Based on Isoniazid and Different Bridged Groups

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Two coordination polymers of [CuSCN(INH)] n (1) and [CuCl(INH)] n (2) have been synthesized (where INH = isoniazid). Their crystal structures have been determined by X-ray single crystal diffraction and both of them belong to monoclinic system. The Cu(I) ions in 1 and 2 all adopt distorted tetrahedral geometries. The complex 1 belongs to Cc space group and the cell parameters are: a = 44.370(2) Å, b = 3.811(3) Å, c = 30.2800(19) Å, β = 132.87(3)° and Z = 4. The Cu(I) ion in 1 is coordinated to three SCN groups and one INH ligand and such coordination model result in a 2D networks construction. Complex 2 crystallizes in the P21/c space group and the cell parameters are: a = 7.0319(13) Å, b = 18.367(3) Å, c = 6.0644(11) Å, β = 93.466(2)° and Z = 4. Each copper atom in 2 is ligated by two INH ligands and two chlorine groups. Two copper atoms are asymmetrically bridged by two chlorine ligands to form a Cu2Cl2 unit. Each Cu2Cl2 fragment is bridged by four INH groups to form a 2D layer structure.

Graphical Abstract

Two 2D Cu (I) coordination polymers based on isoniazid and different bridged groups, [CuSCN(INH))] n and [CuCl(INH)] n were synthesized and characterized.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Eddaoudi M, Moler DB, Li HL, Chen BL, Reineke TM, O’Keeffe M, Yaghi OM (2001) Acc Chem Res 34:319

    Article  CAS  Google Scholar 

  2. Mrozinski J (2005) Coord Chem Rev 249:2534

    Article  CAS  Google Scholar 

  3. Sudik AC, Cote AP, Wong-Foy AG, O’Keeffe M, Yaghi OM (2006) Angew Chem Int Ed 45:2528

    Article  CAS  Google Scholar 

  4. Robin AY, Fromm KM (2006) Coord Chem Rev 250:2127

    Article  CAS  Google Scholar 

  5. Zhang ML, Li DS, Wang JJ, Fu F, Du M, Wu YP (2009) Dalton Trans 27:5355

    Article  Google Scholar 

  6. Wu MF, Zheng FK, Wu AQ, Li Y, Wang MS, Zhou WW, Chen F, Guo GC, Huang JS (2010) Cryst Eng Commun 12:260

    Article  CAS  Google Scholar 

  7. Xu J, Bai ZS, Okamura TA, Chen MS, Sun WY, Ueyama N (2009) Polyhedron 28:2480

    Article  CAS  Google Scholar 

  8. Sun DF, Collins DJ, Ke YX, Zhou HC (2006) Chem Eur J 12:3768

    Article  CAS  Google Scholar 

  9. Rosi NL, Eckert J, Eddaoudi M, Vodak DT, Kim J, O’Keeffe M, Yaghi OM (2003) Science 300:1127

    Article  CAS  Google Scholar 

  10. Wang ZQ, Kravtsov VC, Zaworotko MJ (2005) Angew Chem Int Ed Engl 44:2877

    Article  CAS  Google Scholar 

  11. Hu S, Zhang JP, Li HX, Tong ML, Chen XM, Kitagawa S (2007) Cryst Growth Des 7:2286

    Article  CAS  Google Scholar 

  12. Fu F, Li DS, Gao XM, Du M, Wu YP, Zhang XN, Meng CX (2010) Cryst Eng Commun 12:1227

    Article  CAS  Google Scholar 

  13. Rao CNR, Natarajan S, Vaidhyanathan R (2004) Angew Chem Int Ed Engl 43:1466

    Article  CAS  Google Scholar 

  14. Su Z, Xu J, Fan J, Liu DJ, Chu Q, Chen MS, Chen SS, Liu GX, Wang XF, Sun WY (2009) Cryst Growth Des 9:2801

    Article  CAS  Google Scholar 

  15. Li H, Eddaoudi M, O’keeffe M, Yaghi OM (1999) Nature 402:276

    Article  CAS  Google Scholar 

  16. Rather B, Moulton B, Walsh RDB, Zaworotko MJ (2002) Chem Commun 6:694

    Article  Google Scholar 

  17. Lin ZJ, Slawin AMZ, Morris RE (2007) J Am Chem Soc 129:4880

    Article  CAS  Google Scholar 

  18. Safavi A, Karimi MA, Nezhad MRH (2003) J Pharm Biomed Anal 30:1499

    Article  CAS  Google Scholar 

  19. Song ZH, Lü JH, Zhao TZ (2001) Talanta 53:1171

    Article  CAS  Google Scholar 

  20. Freitas MCR, António JMS, Ziolli RL, Yoshida MI, Rey NA, Diniz R (2011) Polyhedron 30:1922

    Article  CAS  Google Scholar 

  21. Hanson JC, Camerman N, Camerman A (1981) J Med Chem 24:1369

    Article  CAS  Google Scholar 

  22. Miller KM, McCullough SM, Lepekhina EA, Thibau IJ, Pike RD (2011) Inorg Chem 50:7239

    Article  CAS  Google Scholar 

  23. Peng R, Li M, Li D (2010) Coord Chem Rev 254:1

    Article  CAS  Google Scholar 

  24. Jiang ZJ, Tang GD, Zhang Y, Zhang ZC, Lu LD (2010) Chinese J Inorg Chem 26:323

    CAS  Google Scholar 

  25. Jiang ZJ, Lu LD, Wu XD, Yang XJ (2009) Chinese J Inorg Chem 25:746

    CAS  Google Scholar 

  26. Bruker (2000) SMART and SAINT.Bruker AXS Inc, Madison

  27. Sheldrick GM (2000) SADABS. University of Göttingen, Germany

    Google Scholar 

  28. Sheldrick GM (1997) SHELXS97 and SHELXL97. University of Göttingen, Germany

    Google Scholar 

  29. Sheldrick GM (2010) Acta Cryst A64:112

    Google Scholar 

  30. Goher MAS, Mautner FA (1999) Polyhedron 18:1805

    Article  CAS  Google Scholar 

  31. Morshedi M, Amirnasr M, Triki S, Khalaji AD (2011) J Chem Crystallogr 41:39

    Article  CAS  Google Scholar 

  32. Näther C, Greve J, Jeba I, Wickleder C (2003) Solid State Sci 5:1167

    Article  Google Scholar 

  33. Dehno Khalaji A, Weil M, Hadadzadeh H, Daryanavard M (2009) Inorg Chim Acta 362:4837

    Article  CAS  Google Scholar 

  34. Teichert O, Sheldrick WS (1999) Z Anorg Allg Chem 625:1860

    Article  CAS  Google Scholar 

  35. Henary M, Wootton JL, Khan SI, Zink JI (1997) Inorg Chem 36:796

    Article  CAS  Google Scholar 

  36. Robin AY, Fromm KM, Goesmann H, Bernardinelli G (2003) Cryst Eng Commun 5(71):405

    Article  CAS  Google Scholar 

  37. Yaghi OM, Li G (1995) Angew Chem Int Ed Engl 34(2):207

    Article  CAS  Google Scholar 

  38. Lu J, Crisci G, Niu T, Jacobson AJ (1997) Inorg Chem 36:5140

    Article  CAS  Google Scholar 

  39. Jalbout AF, Li XH, Hassan MR, Golzar Hossain GM (2008) Transition Met Chem 33:597

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by Fund of Jiangsu Key Laboratory for Chemistry of Low-dimensional Materials (JSKC12113).

Author information

Authors and Affiliations

  1. Jiangsu Key Laboratory for the Chemistry of Low-Dimensional Materials, Huaiyin Normal University, Huai’an, 223300, Jiangsu, People’s Republic of China

    Zhengjing Jiang, Pusu Zhao, Rongqing Li, Litao An, Zaichao Zhang & Jian Xu

  2. Jiangsu Key Laboratory for Biomassbased Energy and Enzyme Technology, Huaiyin Normal University, Huai’an, 223300, Jiangsu, People’s Republic of China

    Zhengjing Jiang, Pusu Zhao, Rongqing Li, Litao An, Zaichao Zhang & Jian Xu

Authors
  1. Zhengjing Jiang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Pusu Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Rongqing Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Litao An
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Zaichao Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Jian Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Zhengjing Jiang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Jiang, Z., Zhao, P., Li, R. et al. Two Distinct Cu(I) Coordination Polymers Based on Isoniazid and Different Bridged Groups. J Chem Crystallogr 43, 463–470 (2013). https://doi.org/10.1007/s10870-013-0442-x

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-013-0442-x

Keywords

Search

Navigation