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Structure of New Layered Bimetallic Hydrogenoselenite Copper Selenium

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Abstract

The structure of a newly layered copper selenium hydrogenoselenite [Cu(HSeO3)2Cu0.335Se0.582Cl3(H2O)3] has been solved from single crystal X-ray diffraction data and refined to a final reliability factor R 1 = 0.038. It was found having an orthorhombic space group Pna21, with a = 9.0743(4) Å, b = 7.1753(4) Å, c = 17.7246(9) Å, V = 1154.06(10) Å3, and Z = 4. This structure is three-dimensional but it may be described as a bi-dimensional structure made of layers, parallel to the (010) plane, which contain copper atoms and (HSeO3)− anions. The sheets are interconnected by [CuCl3(H2O)3] groups. The Se and Cu oxidation state was evaluated using bond valence sum calculations. The presence of hydrogenoselenites (νSe–O–H, 1,222 cm−1) was confirmed by IR and Raman spectra. The dielectric constant at different frequencies and temperatures revealed a phase transition at 383 K.

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Authors and Affiliations

  1. Laboratoire des Sciences des Matériaux et d’Environnement, Faculté des Sciences de Sfax, B.P. 802, 3018, Sfax, Tunisia

    H. Belgaroui, M. Loukil, A. Kabadou & A. Ben Salah

  2. Laboratoire des Matériaux Ferroélectriques, Faculté des Sciences de Sfax, B.P. 802, 3018, Sfax, Tunisia

    H. Khemakhem

Authors
  1. H. Belgaroui
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  2. M. Loukil
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  3. A. Kabadou
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  4. H. Khemakhem
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  5. A. Ben Salah
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Correspondence to M. Loukil.

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Belgaroui, H., Loukil, M., Kabadou, A. et al. Structure of New Layered Bimetallic Hydrogenoselenite Copper Selenium. J Chem Crystallogr 43, 352–359 (2013). https://doi.org/10.1007/s10870-013-0427-9

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  • DOI: https://doi.org/10.1007/s10870-013-0427-9

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