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Zinc(II), Cadmium(II) and Copper(II) Complexes of a Pyridine Containing Tetrazole Ligand: Synthesis, Crystal Structures and Spectral Properties

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Abstract

Reactions of 1-[2-(1-naphthyl-1H-tetrazole-5-sulfhydryl)]methyl-5-pyridine (L) with ZnCl2, CdCl2·2.5H2O and CuBr2, three complexes [ZnLCl2] (1), [CdL 2(SCN)2] (2) and [CuL 2Br2] (3) have been synthesized and characterized by X-ray diffraction, elemental analysis and IR spectroscopy. In complex 1, the C–H···Cl intermolecular hydrogen bonds have governed the supramolecular contacts and made it into a 3D supramolecular structure, which can be rationalized to be a (4466) topology when the centroid of each molecular was treated as a five-connected node with five other molecules around it. There exist C–H···S and C–H···N hydrogen bonds in complex 2, which make the whole molecular into a 2D sheet structure with topological symbol of (63), when the centroid of each molecular was treated as a six-connected node with six other molecules around it. In complex 3, the hydrogen bond links the molecular into 1D chain structure and the ligand connects one metal ion through its N atom only from the pyridine ring of the L, while the ligand connects one metal ion through both its N atom from the pyridine ring and the N atom from the tetrazole ring in complex 1 and 2. Also the photoluminescence properties at room temperature for complex 1 and 2 have been investigated.

Graphical Abstract

Three complexes, Zinc(II), Cadmium(II) and Copper(II) complexes derived from tetrazole ligand containing pyridine group, have been obtained, their structures and spectral properties have been studied.

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References

  1. Khlobystov AN, Blake AJ, Champness NR, Lemenovskii DA, Majouga AG, Zyk NV, Schröder M (2001) Coord Chem Rev 222:155

    CAS  Google Scholar 

  2. Ye BH, Tong ML, Chen XM (2005) Coord Chem Rev 249:545

    CAS  Google Scholar 

  3. Zhang YN, Liu P, Wang YY, Wu LY, Pang LY, Shi QZ (2011) Cryst Growth Des 11:1531

    CAS  Google Scholar 

  4. Gong Y, Li J, Qin JB, Wu T, Cao R, Li JH (2011) Cryst Growth Des 11:1662

    CAS  Google Scholar 

  5. Li DS, Zhang P, Zhao J, Fang ZF, Du M, Zou K, Mu YQ (2012) Cryst Growth Des 12:1697

    CAS  Google Scholar 

  6. Allendorf MD, Bauer CA, Bhakta RK, Houk RJT (2009) Chem Soc Rev 38:1330

    CAS  Google Scholar 

  7. Cariati E, Pizzotti M, Roberto D, Tessore F, Ugo R (2006) Coord Chem Rev 250:1201

    Google Scholar 

  8. Evans OR, Lin WB (2001) Chem Mater 13:2705

    CAS  Google Scholar 

  9. Kurmoo M (2009) Chem Soc Rev 38:1353

    CAS  Google Scholar 

  10. Sato O (2003) Acc Chem Res 36:692

    CAS  Google Scholar 

  11. Gao EQ, Yue YF, Bai SQ, He Z, Yan CH (2004) J Am Chem Soc 126:1419

    CAS  Google Scholar 

  12. Wang XY, Wang ZM, Gao S (2008) Chem Commun 3:281

    Google Scholar 

  13. Cheng XN, Zhang WX, Lin YY, Zheng YZ, Chen XM (2007) Adv Mater 19:1494

    CAS  Google Scholar 

  14. Sudik AC, Millward AR, Ockwig NW, Cote AP, Kim J, Yaghi OM (2005) J Am Chem Soc 127:7110

    CAS  Google Scholar 

  15. Dincă M, Dailly A, Liu Y, Brown CM, Neumann DA, Long JR (2006) J Am Chem Soc 128:16876

    Google Scholar 

  16. Ma SQ, Sun DF, Wang XS, Zhou HC (2007) Angew Chem Int Ed 46:4670

    Google Scholar 

  17. Li JR, Kuppler RJ, Zhou HC (2009) Chem Soc Rev 38:1477

    CAS  Google Scholar 

  18. Kar P, Haldar R, Gύmez-García CJ, Ghosh A (2012) Inorg Chem 51:4265

    CAS  Google Scholar 

  19. Halper SR, Do L, Stork JR, Cohen SM (2006) J Am Chem Soc 128:15255

    CAS  Google Scholar 

  20. Sun R, Wang S, Xing H, Bai JF, Li YZ, Pan Y, You XZ (2007) Inorg Chem 46:8451

    CAS  Google Scholar 

  21. Mahmoudi G, Morsali A (2007) CrystEngComm 9:1062

    CAS  Google Scholar 

  22. Bu XH, Xie YB, Li JR, Zhang RH (2003) Inorg Chem 42:7422

    CAS  Google Scholar 

  23. Robin AY, Fromm KM, Goesmann H, Bernardinelli G (2003) CrystEngComm 5:405

    CAS  Google Scholar 

  24. Liu PP, Cheng AL, Yue Q, Liu N, Sun WW, Gao EQ (2008) Cryst Growth Des 8:1668

    CAS  Google Scholar 

  25. Hu TL, Zou RQ, Li JR, Bu XH (2008) Dalton Trans. 10:1302

    Google Scholar 

  26. Hagrman PJ, Hagramn DJ (1999) Angew Chem Int Ed 38:2638

    Google Scholar 

  27. Kanoo P, Gurunatha KL, Maji TK (2009) Cryst Growth Des 9:4147

    CAS  Google Scholar 

  28. Chu Q, Liu GX, Okamura T, Huang YQ, Sun WY, Ueyama N (2008) Polyhedron 27:812

    CAS  Google Scholar 

  29. Su CY, Cai YP, Chen CL, Kang KS (2001) Inorg Chem 40:2210

    CAS  Google Scholar 

  30. Li L, Hu TL, Li JR, Wang DZ, Zeng YF, Bu XH (2007) CrystEngComm 9:412

    CAS  Google Scholar 

  31. Wang W, Niu X, Gao Y, Zhu Y, Li G, Lu H, Tang M (2010) Cryst Growth Des 10:4050

    CAS  Google Scholar 

  32. Klimgele MH, Brooker S (2003) Coord Chem Rev 241:119

    Google Scholar 

  33. Ferrer S, Haasnoot JG, Reedijk J, Müller E, Cingi MBMA, Lanfranchi M, Lanfredi M, Ribas J (2000) Inorg Chem 39:1859

    CAS  Google Scholar 

  34. Zhai QG, Wu XY, Chen SM, Lu CZ, Yang WB (2006) Cryst Growth Des 6:2126

    CAS  Google Scholar 

  35. Qin L, Hu JS, Huang LF, Li YZ, Guo ZJ, Zheng HG (2010) Cryst Growth Des 10:4176

    CAS  Google Scholar 

  36. Itoh S, Bandoh H, Nagatomo S, Kitagawa T, Fukuzumi S (1999) J Am Chem Soc 121:8945

    CAS  Google Scholar 

  37. Shiren K, Ogo S, Fujinami S, Hayashi H (2000) J Am Chem Soc 122:254

    CAS  Google Scholar 

  38. Wang CC, Yang CC, Yeh CT, Cheng KY, Chang PC, Ho ML, Lee GH, Shih WJ, Sheu HS (2011) Inorg Chem 50:597

    CAS  Google Scholar 

  39. Zhao H, Qu ZR, Ye HY, Xiong RG (2008) Chem Soc Rev 37:84

    Google Scholar 

  40. Tong XL, Hu TL, Zhao JP, Wang YK, Zhang H, Bu XH (2010) Chem Commun 46:8543

    CAS  Google Scholar 

  41. Tong XL, Wang DZ, Hu TL, Song WC, Tao Y, Bu XH (2009) Cryst Growth Des 9:2280

    CAS  Google Scholar 

  42. Dong P, Zhang QK, Wang F, Chen SC, Wu XY, Zhao ZG, Lu CZ (2010) Cryst Growth Des 10:3218

    CAS  Google Scholar 

  43. Jiang T, Zhang XM (2008) Cryst Growth Des 8:3077

    CAS  Google Scholar 

  44. Wu T, Yi BH, Li D (2005) Inorg Chem 44:4130

    CAS  Google Scholar 

  45. Dincă M, Long JR (2008) Angew Chem Int Ed 47:6777

    Google Scholar 

  46. Lin Q, Luo R, Cui WH, Wei TB, Zhang YM (2006) Chinese J Synth Chem 14:44

    CAS  Google Scholar 

  47. Sheldrick GM (2008) Acta Cryst A64:112

    Google Scholar 

  48. Blatov VA, Carlucci L, Ciani G, Proserpio DM (2004) CrystEngComm 6:377

    CAS  Google Scholar 

  49. Kumar DK, Ballabh A, Jose DA, Dastidar P, Das A (2005) Cryst Growth Des 5:651

    CAS  Google Scholar 

  50. Stephenson MD, Hardiem MJ (2006) Cryst Growth Des 6:423

    CAS  Google Scholar 

  51. Zhang XQ, Yu Q, Bian HD, Bao XG, Liang H (2009) J Coord Chem 62:2108

    CAS  Google Scholar 

  52. Tong XL, Xin JH (2011) Z Anorg Allg Chem 637:2265

    CAS  Google Scholar 

  53. Chen LZ, Zou J, Gao YM, Wan S, Huang MN (2011) J Coord Chem 64:715

    CAS  Google Scholar 

  54. Xu GH, Hang T, Pan KJ, Ye Q (2011) J Coord Chem 64:2457

    Google Scholar 

  55. Tong XL, Hu TL, Zhao JP, Wang YK, Zhang H, Bu XH (2010) Chem Commun 46:8543

    CAS  Google Scholar 

  56. Wu Q, Esteghamatian M, Hu NX, Popovic ZD, Enright G, Tao Y, D’Iorio M, Wang S (2000) Chem Mater 12:79

    CAS  Google Scholar 

  57. Cohen BW, Lovaasen BM, Simpson CK, Cummings SD, Dallinger RF, Hopkins MD (2010) Inorg Chem 49:5777

    CAS  Google Scholar 

  58. Sun Y, Wang S (2010) Inorg Chem 49:4394

    CAS  Google Scholar 

  59. Xu C, Guo Q, Wang X, Hou H, Fan Y (2011) Cryst Growth Des 11:1869

    CAS  Google Scholar 

  60. McGarrah JE, Kim YJ, Hissler M, Eisenberg R (2001) Inorg Chem 40:4510

    CAS  Google Scholar 

  61. Ciurtin DM, Pschirer NG, Smith MD, Bunz UHF, Loye HC (2001) Chem Mater 13:2743

    CAS  Google Scholar 

  62. Dong YB, Wang HY, Ma JP, Shen DZ, Huang RQ (2005) Inorg Chem 44:4679

    CAS  Google Scholar 

  63. Seward C, Jia WL, Wang RY, Enright GD, Wang SN (2004) Angew Chem Int Ed 43:2933

    CAS  Google Scholar 

  64. Wu CD, Ngo HL, Lin W (2004) Chem Commun 14:1588

    Google Scholar 

  65. Lim NC, Freake HC, Brückner C (2005) Chem Eur J 11:38

    Google Scholar 

  66. Walkup GK, Burdette SC, Lippard SJ, Tsien RY (2000) J Am Chem Soc 122:5644

    CAS  Google Scholar 

  67. Giménez R, Manrique AB, Uriel S, Barbera J, Serrano JL (2004) Chem Commun 18:2064

    Google Scholar 

  68. Yan VWW, Lo KKW (1999) Chem Soc Rev 28:323

    Google Scholar 

  69. Tong YP, Zheng SL, Chen XM (2005) Eur J Inorg Chem 18:3734

    Google Scholar 

Download references

Acknowledgments

This work was financially supported by Project of Jiangxi Provincial Department of Education (Grant No. GJJ12396 and NO.GJJ11140), the Start-up Fund of East China Institute of Technology, and the National Science Foundation of Jiangxi Province (No. 2010GQH0007).

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  1. College of Biology, Chemistry and Material Science, East China Institute of Technology, Fuzhou, 344000, Jiangxi, People’s Republic of China

    Xiao-Lan Tong, Zhang-Gao Le, Min Li, Jian-Hua Xin & Ting Yang

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  1. Xiao-Lan Tong
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  2. Zhang-Gao Le
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  3. Min Li
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  4. Jian-Hua Xin
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Correspondence to Xiao-Lan Tong.

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Tong, XL., Le, ZG., Li, M. et al. Zinc(II), Cadmium(II) and Copper(II) Complexes of a Pyridine Containing Tetrazole Ligand: Synthesis, Crystal Structures and Spectral Properties. J Chem Crystallogr 43, 266–274 (2013). https://doi.org/10.1007/s10870-013-0414-1

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