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Three New Cadmium Complexes Based on 3-Nitrophthalic Acid: Syntheses, Crystal Structures and Fluorescent Properties

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Abstract

Three metal–organic coordinate complexes based on 3-nitrophthalic acid (H2NPA), namely Cd2(H2O)(OH)2(NPA) (1), Cd2(Im)4(NPA)2 (2) and Cd2(Bim)4(H2O)(NPA)2 (3) (Im = imidazole, Bim = benzimidazole), have been obtained by hydrothermal method and characterized by X-ray single crystal structure determination. Structural analysis reveals that complex 1 exhibits 2D layers constructed by polyhedral aggregates. Complex 2 exhibits a dinuclear cadmium structural unit and assembles by hydrogen bonds into a 2D supramolecular architecture. Complex 3 is assembled by NPA2− into layers of a (3,4)-connected dinodal net topology of (4·52)(4·53·72). The fluorescent properties of complexes 1–3 have been investigated.

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Acknowledgments

This project was supported by the Non-metallic Mineral Engineering Research Center of Zhejiang Province (Grant No. ZD2015k05). Honest thanks are also extended to K. C. Wong Magna Fund in Ningbo University.

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  1. Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo, 315211, People’s Republic of China

    Zhen-Xiu Si & Wei Xu

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  1. Zhen-Xiu Si
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  2. Wei Xu
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Correspondence to Wei Xu.

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Si, ZX., Xu, W. Three New Cadmium Complexes Based on 3-Nitrophthalic Acid: Syntheses, Crystal Structures and Fluorescent Properties. J Clust Sci 27, 603–615 (2016). https://doi.org/10.1007/s10876-015-0957-8

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  • DOI: https://doi.org/10.1007/s10876-015-0957-8

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