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Octahedral Complexes of Cobalt(III) and Nickel(II) Incorporating with Unsymmetrical NNO-Donor Hydrazone Ligand: Synthesis and Structural Aspects

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Abstract

Two new octahedral cobalt(III) and nickel(II) complexes, [CoL2]·ClO4 (1) and [NiL2]·H2O·NO3 (2) containing the potentially tridentate Schiff base like hydrazone ligand, N′-[1-(pyridin-2-yl)ethylidene]acetohydrazide (L) (1:1 condensation product of acetichydrazide and 2-acetylpyridine) were synthesized and characterized by spectral a well as thermal analysis and single crystal X-ray diffractometry. Structural investigation shows that in both complexes, the central Co or Ni atom belongs into N4O2 coordination sphere, developed with the NNO donor sets of two independently hydrazone units. The corresponding M–N(pyridine) bonds being significantly longer than the M–N(imino) bonds, Co1–N1 and Co1–N4 [1.934(3) and 1.926(3) Å] for 1 and Ni1–N1 and Ni1–N4 [2.076(3) and 2.085(3) Å] for 2, Co1–N2 and Co1–N5 [1.846(3) and 1.854(3) Å] for 1 and Ni1–N2 and Ni1–N5 [2.001(3) and 1.972(3) Å] for 2 respectively.

Graphical Abstract

Two new octahedral cobalt(III) and nickel(II) complexes containing the potentially tridentate hydrazone ligand, N’-[1-(pyridin-2-yl)ethylidene]acetohydrazide (L) were synthesized and characterized by IR and UV–Vis spectra as well as thermal analysis and single crystal X-ray diffractometry.

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Acknowledgments

The authors gratefully acknowledge financial support from the National Science Council of Taiwan.

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Authors and Affiliations

  1. Department of Chemistry, National Changhua University of Education, Changhua, 50058, Taiwan

    Amitabha Datta & Jui-Hsien Huang

  2. Department of Inorganic and Radiation Chemistry, Institute of Chemistry, University of Silesia, 9th Szkolna Street, 40-006, Katowice, Poland

    Barbara Machura

Authors
  1. Amitabha Datta
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  2. Jui-Hsien Huang
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  3. Barbara Machura
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Correspondence to Amitabha Datta or Jui-Hsien Huang.

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Datta, A., Huang, JH. & Machura, B. Octahedral Complexes of Cobalt(III) and Nickel(II) Incorporating with Unsymmetrical NNO-Donor Hydrazone Ligand: Synthesis and Structural Aspects. J Chem Crystallogr 42, 691–696 (2012). https://doi.org/10.1007/s10870-012-0301-1

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  • DOI: https://doi.org/10.1007/s10870-012-0301-1

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