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Synthesis, Spectral Properties and Structure of New Novel 3,3′-Dibenzoyl-1,1′-(propan-1,3-diyl)-bisthiourea

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Abstract

A new 3,3′-dibenzoyl-1,1′-propan-1,3-diyl)bisthiourea was synthesized by using benzoylisothiocyanate with 1,3-diaminopropane in aprotic solvent. The structure was determinated by means of FT-IR, 1H-NMR, 13C-NMR and mass spectroscopic techniques. The crystal structure of 3,3′-dibenzoyl-1,1′-(propan-1,3-diyl)bisthiourea has also been examined by using X-ray crystallographic techniques and found to be crystallized in the monoclinic space group P2 1 /c with the unit cell parameters: a = 5.968(1) Å, b = 19.471(2) Å, c = 16.585(2) Å, β = 98.32(1)°, V = 1907.0(4) Å3, Dx = 1.395 g cm−3, and Z = 4 respectively.

Index Abstract

A new 3,3′-dibenzoyl-1,1′-propan-1,3-diyl)bisthiourea was synthesized by using benzoylisothiocyanate with 1,3-diaminopropane in aprotic solvent. The structure was determinated by means of FT-IR, 1H-NMR, 13C-NMR and mass spectroscopic techniques. The crystal structure of 3,3′-dibenzoyl-1,1′-(propan-1,3-diyl)bisthiourea has also been examined by using X-ray crystallographic techniques and found to be crystallized in the monoclinic space group P2 1 /c with the unit cell parameters: a = 5.968(1) Å, b = 19.471(2) Å, c = 16.585(2) Å, β = 98.32(1)°, V = 1907.0(4) Å3, Dx = 1.395 g cm−3, and Z = 4 respectively.

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Notes

  1. Further information may be obtained from: Cambridge Crystallographic Data Center (CCDC), 12 Union Road, Cambridge CB21EZ, UK, by quoting the depository number CCDC-780265. E-mail: deposit@ccdc.cam. ac.uk

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Acknowledgments

The synthesis section of this study is a part of Dogan AYKAÇ’s Ms Thesis and was supported by Çanakkale Onsekiz Mart University Research Fund (Project No: BAP-2008-35).

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Authors and Affiliations

  1. Department of Chemistry, Canakkale Onsekiz Mart University, 17100, Canakkale, Turkey

    Fatma Aydın & Doğan Aykaç

  2. Department of Physics, Ankara University, Tandoğan, 06100, Ankara, Turkey

    Hüseyin Ünver

  3. Department of Physics, Faculty of Science and Arts, Ondokuz Mayıs University, Kurupelit, 55139, Samsun, Turkey

    Nazan Ocak İskeleli

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  1. Fatma Aydın
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  2. Doğan Aykaç
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  3. Hüseyin Ünver
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  4. Nazan Ocak İskeleli
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Correspondence to Fatma Aydın.

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Aydın, F., Aykaç, D., Ünver, H. et al. Synthesis, Spectral Properties and Structure of New Novel 3,3′-Dibenzoyl-1,1′-(propan-1,3-diyl)-bisthiourea. J Chem Crystallogr 42, 381–387 (2012). https://doi.org/10.1007/s10870-011-0258-5

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  • DOI: https://doi.org/10.1007/s10870-011-0258-5

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