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Microwave Synthesis and Crystal Structure of 2-(p-Tolylimino-methyl)-phenol-copper (II)

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Abstract

2-(p-Tolylimino-methyl)-phenol-copper (II) has been synthesized and its structure determined by X-ray diffraction. It crystallizes in the monoclinic system, space group P2(1)/c, with the cell parameters a = 12.0266 (15) Å, b = 27.714 (2) Å, c = 11.0043 (11) Å, α = γ = 90.00°, β = 107.7510 (10)°, V = 3493.1 (6) Å3 and Z = 6. The Cu atom is surrounded by two O atoms and two N atoms from two 2-(p-Tolylimino-methyl)-phenol molecules to form a tetrahedron coordination environment. The complex is linked into a column by weak intermolecular interactions.

Graphical Abstract

2-(p-Tolylimino-methyl)-phenol-copper(II) has been synthesized under microwave condition and its structure determined by X-ray diffraction.

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Acknowledgments

The work was co-financed by grants (Projects 30772627) from National Natural Science Foundation of China and (Projects 09KJD150005) from Natural Science Foundation of Jiangsu Province, China.

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Authors and Affiliations

  1. Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Xuzhou Normal University, Xuzhou, 221116, People’s Republic of China

    Suo-Ping Xu & Yuan Pei

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  1. Suo-Ping Xu
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  2. Yuan Pei
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Correspondence to Suo-Ping Xu.

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Xu, SP., Pei, Y. Microwave Synthesis and Crystal Structure of 2-(p-Tolylimino-methyl)-phenol-copper (II). J Chem Crystallogr 42, 330–332 (2012). https://doi.org/10.1007/s10870-011-0247-8

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  • DOI: https://doi.org/10.1007/s10870-011-0247-8

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