Skip to main content
SpringerLink
Log in

One-Dimensional Polymers Constructed with Paddle-Wheel Dinuclear Copper(II) Bridged by 4,4′-Bipyridine

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The coordination compound {[Cu(NAP)2](4,4′-bpy)1/2}·DMF (1) was prepared by the reaction of α-naphthoic acid, 4,4′-bipyridine and Copper(II) acetate hydrate in basic solution, and was fully characterized by X-ray diffraction, element analysis, FTIR and TG analysis. Crystals of compound 1 belongs to the monoclinic crystal system, space group C2/c; a = 17.460(4) Å, b = 13.928(3) Å, c = 21.240(4) Å, β = 93.83(3), V = 5153.7 Å3, Z = 8. The structure analyses of 1 show a one-dimensional chain structure where the binuclear structural units [Cu2(NAP)4] are bridged by 4,4′-bipyridine molecules. Furthermore, the 1D chains are assembled to form 2D supramolecular sheet by intermolecular π···π stacking interactions between naphthalene rings.

Graphical Abstract

A new metal coordination polymer {[Cu(NAP)2](4,4′-bpy)1/2}·DMF was synthesized. The title complex features binuclear structural units [Cu2(NAP)4] which bridged by 4,4′-bipyridine ligands to extend one-dimensional chain structure, and was further linked into two-dimensional supramolecular sheet by intermolecular π···π stacking interactions between naphthalene rings.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Daniel M, Daniel RM, Jaume V (2007) Chem Soc Rev 36:770

    Article  Google Scholar 

  2. Klein N, Denkovska I, Gedrich K, Stoeck U, Henschel A, Mueller U, Kaskel S (2009) Angew Chem Int Ed 48:1

    Google Scholar 

  3. McKinlay AC, Morris RE, Horcajada P, Férey G, Gref R, Counreur P, Serre C (2010) Angew Chem Int Ed 49:6260

    Article  CAS  Google Scholar 

  4. Bauer CA, Timofeeva TV, Settersten TB, Patterson BD, Liu VH, Simmons BA, Allendorf MD (2007) J Am Chem Soc 129:7136

    Article  CAS  Google Scholar 

  5. Peedikakkal AMP, Song YM, Xiong RG, Gao S, Vittal JJ (2010) Eur J Inorg Chem 3856

  6. Li JR, Kuppler RJ, Zhou HC (2009) Chem Soc Rev 38:1477

    Article  CAS  Google Scholar 

  7. Tanabe KK, Cohen SM (2009) Angew Chem Int Ed 48:7424

    Article  CAS  Google Scholar 

  8. Baca SG, Malaestean IL, Keene TD, Adams H, War MD, Hauser J, Neels A, Decurtins S (2008) Inorg Chem 47:11108

    Article  CAS  Google Scholar 

  9. Roubeau O, Clérac R (2008) Eur J Inorg Chem 4325

  10. Bai YL, Tao J, Huang RB, Zheng LS (2008) Angew Chem Int Ed 47:5344

    Article  CAS  Google Scholar 

  11. Thompson LK (2002) Coord Chem Rev 233–234:193

    Article  Google Scholar 

  12. Hu HL, Suen MC, Yeh CW, Chen JD (2005) Polyhedron 24:1497

    Article  CAS  Google Scholar 

  13. Wang JJ, Chang Z, Zhang AS, Hu TL, Bu XH (2010) Inorg Chim Acta 363:1377

    Article  CAS  Google Scholar 

  14. Hou HW, Xie LX, Li G, Ge TZ, Fan YT, Zhu Y (2004) New J Chem 28:191

    Article  CAS  Google Scholar 

  15. Dong YB, Ma JP, Smith MD, Huang RQ, Tang B, Chen DZ, zur Loye HC (2002) Solid State Sci 4:1313

    Article  CAS  Google Scholar 

  16. Takamizawa S, Nataka E, Akatsuka T, Miyake R, Kakizaki Y, Takeuchi H, Maruta G, Takeda S (2010) J Am Chem Soc 132:3783

    Article  CAS  Google Scholar 

  17. Belcher WJ, Longstaff CA, Neckenig MR, Steed JW (2002) Chem Commun 1602

  18. Pramanik S, Zheng C, Zhang X, Emge TJ, Li J (2011) J Am Chem Soc 133:4153

    Article  CAS  Google Scholar 

  19. Aijaz A, Lama P, Bharadwaj PK (2010) Eur J Inorg Chem 3829

  20. Verat AY, Ould-Moussa N, Jeanneau E, Guennic BL, Bousseksou A, Borshch SA, Matouzenko GS (2009) Chem Eur J 15:10070

    Article  CAS  Google Scholar 

  21. Felloni M, Blake AJ, Hubberstey P, Wilson C, Schröder M (2009) Cryst Growth Des 9:4685

    Article  CAS  Google Scholar 

  22. Sheldrick GM (1997) SHELXS-97 and SHELXL-97, program for refinement of crystal structures. University of Göttingen, Göttingen

    Google Scholar 

  23. Addison AW, Rao TN (1984) J Chem Soc Dalton Trans 1349

  24. Nakamoto K (2009) Infrared and Raman spectra of inorganic and coordination compounds: part B, 6th edn. Wiley Interscience, New York, p 64

    Google Scholar 

Download references

Acknowledgments

This project was supported by the Scientific Research Fund of Zhejiang Provincial Education Department (Grant No. Y201017782) and the Scientific Research Fund of Ningbo University (Grant No. XKL09078). The honest thanks are also extended to K. C. Wong Magna Fund in Ningbo University.

Author information

Authors and Affiliations

  1. Center of Applied Solid State Chemistry Research, Ningbo University, Ningbo, 315211, People’s Republic of China

    Wei Xu & Yue-Qing Zheng

Authors
  1. Wei Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yue-Qing Zheng
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Yue-Qing Zheng.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Xu, W., Zheng, YQ. One-Dimensional Polymers Constructed with Paddle-Wheel Dinuclear Copper(II) Bridged by 4,4′-Bipyridine. J Chem Crystallogr 42, 313–317 (2012). https://doi.org/10.1007/s10870-011-0244-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-011-0244-y

Keywords

Search

Navigation