Skip to main content
SpringerLink
Log in

2D s-d Mixed-Metal Coordination Polymer Containing Potassium, Chromium(III) and Dipicolinate Ions: Preparation and Crystal Structure

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The reaction of pyridine-2,6-dicarboxylic acid (dipicolinic acid, dipicH2) with potassium tetraperoxochromate(V) in the mixture of water and ethanol led to the formation of a 2D s-d mixed-metal coordination polymer of {K[Cr(dipic)2]}n (1). The compound was characterized by spectroscopic methods (IR, Raman, UV/Vis). Single crystal X-ray diffraction analysis revealed that dipicolinate ligand is coordinated to the chromium(III) ion in an O,N,O′-tridentate fashion, while its uncoordinated and coordinated carboxylate O atoms (with respect to Cr(III) ion) are in turn bound to potassium ions. Therefore, each dipicolinate ligand bridges two potassium ions and a chromium(III) ion between them, giving rise to a 2D coordination network. The coordination of chromium(III) ions is octahedral, while the coordination number of potassium ions is 8. The coordination networks are in turn assembled only by π–π stacking interactions into a 3D structure.

Graphical Abstract

2D mixed-metal coordination polymer, containing potassium, chromium(III) and dipicolinate ions, was prepared and characterized by spectroscopic methods (IR, Raman, UV/Vis) and its crystal structure was determined by single crystal X-ray structural analysis.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2

Similar content being viewed by others

References

  1. Chatterjee M, Maji M, Ghosh S, Mak TCW (1998) J Chem Soc Dalton Trans 3641

  2. Nathan LC, Mai TD (2000) J Chem Crystallogr 30:509

    Article  CAS  Google Scholar 

  3. Nathan LC (1993) Inorg Chem 3:415

    Google Scholar 

  4. Yang L, Crans DC, Miller SM, la Cour A, Anderson OP, Kaszynski PM, Godzala ME III, Austin LD, Willsky GR (2002) Inorg Chem 41:4859

    Article  CAS  Google Scholar 

  5. Park H, Lough AJ, Kim JC, Jeong MH, Kang YS (2007) Inorg Chim Acta 360:2819

    Article  CAS  Google Scholar 

  6. Liu SH, Li YZ, Meng QJ (2005) Acta Crystallogr E61:1183

    Google Scholar 

  7. MacDonald JC, Dorrestein PC, Pilley MM, Foote MM, Lundburg JL, Henning RW, Schultz AJ, Manson JL (2000) J Am Chem Soc 122:11692

    Article  CAS  Google Scholar 

  8. Harrison WTA, Ramadevi P, Kumeresan S (2006) Acta Crystallogr E62:513

    Google Scholar 

  9. Devereux M, Cann MM, Leon V, Kee VM, Ball RJ (2002) Polyhedron 21:1063

    Article  CAS  Google Scholar 

  10. Ranjbar M, Aghabozorg H, Moghimi A, Yanovsky A (2001) Z Kristallogr New Cryst Struct 216:626

    CAS  Google Scholar 

  11. Aghabozorg H, Derikvand Z, Olmstead MM, Attar Gharamaleki J (2008) Acta Crystallogr E64:m1234

    CAS  Google Scholar 

  12. Soleimannejad J, Aghabozorg H, Hooshmand S (2008) Acta Crystallogr E64:m564

    CAS  Google Scholar 

  13. Aghajani Z, Aghabozorg H, Sadr-Khanlou E, Shokrollahi A, Derki S, Shamsipur M (2009) J Iran Chem Soc 6:373

    CAS  Google Scholar 

  14. Furst W, Gouzerh P, Jeannin Y (1979) J Coord Chem 8:237

    Article  Google Scholar 

  15. Casellato U, Graziani R, Bonomo RP, Di Bilio AJ (1991) J Chem Soc Dalton Trans 23

  16. Rafizadeh M, Amani V, Neumüller B (2006) Z Anorg Allg Chem 632:2190

    Article  CAS  Google Scholar 

  17. Braga D, Bazzi C, Maini L, Grepioni F (1999) Cryst Eng Comm 1:15

    Google Scholar 

  18. Wieghardt K, Quillitzsch U, Weiss J (1984) Inorg Chim Acta 89:L43

    Article  CAS  Google Scholar 

  19. Gonzalez-Baro AC, Pis-Diez R, Piro OE, Parajon-Costa BS (2008) Polyhedron 27:502

    Article  CAS  Google Scholar 

  20. Ou CC, Borowski WJ, Potenza JA, Schugar HJ (1977) Acta Crystallogr B33:3246

    CAS  Google Scholar 

  21. Tabatabaee M, Kukovec BM, Kazeroonizadeh M (2011) Polyhedron 30:1114

    Article  CAS  Google Scholar 

  22. Hakimi M, Maeder M, Lawrance GA (2011) J Coord Chem 64:105

    Article  CAS  Google Scholar 

  23. Hakimi M, Vahedi MH, Rezvaninezhad M, Schuh E, Mohr F (2011) J Sulfur Chem 32:55

    Article  CAS  Google Scholar 

  24. Hakimi M, Yazdanbakhsh M, Heravi MM, Ghassemzadeh M, Neumuller B (2002) Z Anorg Allg Chem 628:1899

    Article  Google Scholar 

  25. Yazdanbakhsh M, Hakimi M, Heravi MM, Ghassemzadeh M, Neumuller B (2004) Z Anorg Allg Chem 630:627

    Article  CAS  Google Scholar 

  26. Yazdanbakhsh M, Hakimi M, Heravi MM, Ghassemzadeh M, Neumuller B (2005) Z Anorg Allg Chem 631:924

    Article  CAS  Google Scholar 

  27. Yazdanbakhsh M, Hakimi M, Heravi MM, Boese R (2006) Z Anorg Allg Chem 632:2201

    Article  CAS  Google Scholar 

  28. Dai Y, Shi W, Zhu XJ, Zhao B, Cheng P (2006) Inorg Chim Acta 359:3353

    Article  CAS  Google Scholar 

  29. Woollins JD (ed) (2010) Inorganic Experiments, 3rd Revised Edition, Wiley-VCH, New York

  30. SAINT (2004) Version 7.12. Bruker AXS Inc, Madison, WI

  31. Sheldrick GM (1996) SADABS. University of Göttingen, Germany

    Google Scholar 

  32. Sheldrick GM (2008) Acta Crystallogr A64:112

    CAS  Google Scholar 

  33. Spek AL (2003) J Appl Crystallogr 36:7

    Article  CAS  Google Scholar 

  34. Farrugia LJ (1997) J Appl Crystallogr 30:565

    Article  CAS  Google Scholar 

  35. Macrae CF, Bruno IJ, Chisholm JA, Edgington PR, McCabe P, Pidcock E, Rodriguez-Monge L, Taylor R, van de Streek J, Wood PA (2008) J Appl Crystallogr 41:466

    Article  CAS  Google Scholar 

  36. Ma C, Chen C, Chen F, Zhang X, Zhu H, Liu Q, Liao D, Li L (2003) Bull Chem Soc Jpn 76:301

    Article  CAS  Google Scholar 

  37. Schwarzenbach D (1972) Helv Chim Acta 55:2990

    Article  CAS  Google Scholar 

  38. Willey GR, Woodman TJ, Fisher M, Drew MGB (1998) Transition Met Chem 23:467

    Article  CAS  Google Scholar 

  39. Chessa G, Marangoni G, Pitteri B, Bertolasi V, Gilli G, Ferretti V (1991) Inorg Chim Acta 185:201

    Article  CAS  Google Scholar 

  40. Schwarzenbach D (1970) Inorg Chem 9:2391

    Article  CAS  Google Scholar 

Download references

Acknowledgment

This research was supported by Payame Noor University, Tehran, Iran.

Author information

Authors and Affiliations

  1. Department of Chemistry, Payame Noor University, 19395-4697, Tehran, Iran

    Mohammad Hakimi

  2. Department of Chemistry, Faculty of Science, Laboratory of General and Inorganic Chemistry, University of Zagreb, Horvatovac 102a, 10000, Zagreb, Croatia

    Boris-Marko Kukovec

  3. Department of Chemistry, School of Science, Kitasato University, 1-15-1 Kitasato, Minami-ku, Sagamihara, Kanagawa, 252-0373, Japan

    Mao Minoura

Authors
  1. Mohammad Hakimi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Boris-Marko Kukovec
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Mao Minoura
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Mohammad Hakimi or Boris-Marko Kukovec.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hakimi, M., Kukovec, BM. & Minoura, M. 2D s-d Mixed-Metal Coordination Polymer Containing Potassium, Chromium(III) and Dipicolinate Ions: Preparation and Crystal Structure. J Chem Crystallogr 42, 290–294 (2012). https://doi.org/10.1007/s10870-011-0242-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-011-0242-0

Keywords

Search

Navigation