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Bis[(2,3,4-Trimethoxy-Benzylidenepropylideneamino)Phenyl]Ether: Synthesis, Characterization and Crystal Structure

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Abstract

New Schiff base compound bis[(2,3,4-trimethoxy-benzylidenepropylideneamino)phenyl]-ether (1) was synthesized and characterized by elemental analyses (CHN), FT-IR and 1H-NMR spectroscopy and single-crystal X-ray diffraction. The title compound 1 crystallizes in triclinic system, space group P-1, with a = 6.8255(4) Å, b = 10.4346(4) Å, c = 19.4166(8) Å, α = 86.588(3)°, β = 85.019(4)°, γ = 89.042(4)°, V = 1375.12(11) Å3 and Z = 2. It displays a trans configuration about the C=N double bonds.

Graphical Abstract

New Schiff base compound bis[(2,3,4-trimethoxy-benzylidenepropylideneamino)phenyl]-ether (1) was synthesized and characterized by elemental analyses (CHN), FT-IR and 1H-NMR spectroscopy and single-crystal X-ray diffraction. The title compound 1 displays a trans configuration about the C=N double bonds.

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Acknowledgments

We acknowledge the Golestan University (GU) for partial support of this work, the institutional research plan No. AVOZ10100521 of the Institute of Physics and the project Praemium Academiae of the Academy of Sciences.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran

    Aliakbar Dehno Khalaji

  2. Institute of Physics of the ASCR, v.v.i., Na Slovance 2, 182 21, Prague 8, Czech Republic

    Karla Fejfarova & Michal Dusek

Authors
  1. Aliakbar Dehno Khalaji
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  2. Karla Fejfarova
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  3. Michal Dusek
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Correspondence to Aliakbar Dehno Khalaji.

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Khalaji, A.D., Fejfarova, K. & Dusek, M. Bis[(2,3,4-Trimethoxy-Benzylidenepropylideneamino)Phenyl]Ether: Synthesis, Characterization and Crystal Structure. J Chem Crystallogr 42, 263–266 (2012). https://doi.org/10.1007/s10870-011-0235-z

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