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Synthesis and Characterization of the Adducts of Bis(O-butyldithiocarbonato)nickel(II) with Substituted Heterocyclic Amines and X-ray Structure of Bis(O-butyldithiocarbonato)bis(4-cyanopyridine)nickel(II)

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Abstract

We report the synthesis and study of a new series of the adducts of Bis(O-butyldithiocarbonato)nickel(II) with substituted heterocyclic amines such as amino and cyanopyridines. Analytical results show that the adducts have 1:2 stoichiometry with general formula M(Xan)2 L 2 (M = Ni(II), Xan = O-butyldithiocarbonate, L = 2-, 3- and 4-aminopyridines, 3- and 4-cyanopyridines). The complexes have been characterized by analytical, magnetic susceptibility measurements, molar conductivity measurements, IR, electronic spectral data and X-ray diffraction analysis. One of the adducts, bis(O-butyldithiocarbonato)bis(4-cyanopyridine)nickel(II), crystallizes in the monoclinic space group P21/c with unit cell parameters : a = 12.546(4), b = 11.495(3), c = 9.351(3) Å, β = 102.73(3)º, Z = 2. Crystal structure was solved by direct methods and refined by full matrix least squares procedures to a final R-value of 0.0299 for 2,788 observed reflections. The packing of layers of molecules is stabilized by weak C–H···N and C–H···π hydrogen bonds.

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References

  1. Gimeno MC, Jambrina E, Laguna A, Murray HH, Terroba R (1996) Inorg Chem Acta 249:69

    Article  CAS  Google Scholar 

  2. Allen FH, Kennard O (1993) Chem Des Autom News 8:31

    Google Scholar 

  3. Victorriano LI, Cortes HB (1996) J Coord Chem 39:231

    Article  Google Scholar 

  4. Rao SR (1971) Xanthates and related compounds. MDekker, New York

    Google Scholar 

  5. Ara I, Behij FE (2003) Trans Met Chem 28:908

    Article  CAS  Google Scholar 

  6. Litipova Sh Z, Khakimova VK, Tukhtaev S (1991) Uzb Khim Zh 2:3

    Google Scholar 

  7. Xiong RG, Yu Zh, Liu CM, You XZ (1997) Polyhedron 16:2667

    Article  CAS  Google Scholar 

  8. Gable RW, Hoskins BF, Winter G (1985) Inorg Chem Acta 96:151

    Article  CAS  Google Scholar 

  9. Reddy PCh, Rangamannar B (1996) J Radional Nucl Chem 213:9

    Article  CAS  Google Scholar 

  10. PCh Reddy, Rangamannar B (1996) J Radioanal Nucl Chem 214:159

    Google Scholar 

  11. Wolf N, Roundhill DM (1994) Polyhedron 13:2801

    Article  CAS  Google Scholar 

  12. Zelmon DE, Gebeyhu Z, Tomlin DC, Thomas M (1998) Mater Res Symp Proc 519:395

    Article  CAS  Google Scholar 

  13. Furniss BS, Hannaford AJ, Smith PWG, Tatchell AR (1989) Vogel’s text book of practical organic chemistry, 5th edn. Pearson Education, London

    Google Scholar 

  14. Sheldrick GM, SHELXS97 (1997) Program for the solution of crystal structures. University of Gottingen, Gottingen

    Google Scholar 

  15. Sheldrick GM, SHELXL97 (1997) Program for the refinement of crystal structures. University of Gottingen, Gottingen

    Google Scholar 

  16. Martin RL, Whitley A (1958) J Chem Soc 1394

  17. Lever ABP (1965) J Inorg Nucl Chem 27:149

    Article  CAS  Google Scholar 

  18. Basolo F, Matousch WR (1953) J Am Chem Soc 75:5663

    Article  CAS  Google Scholar 

  19. Coucouvanis D, Fackler JP (1967) Inorg Chem 6:2047

    Article  CAS  Google Scholar 

  20. Lever ABP (1984) Inorganic electronic spectroscopy. Elsevier, Amsterdam

    Google Scholar 

  21. Farrugia LJ (1997) J Appl Cryst 30:565

    Article  CAS  Google Scholar 

  22. Spek AL (1999) PLATON for windows version. University of Utrecht, Utrecht

    Google Scholar 

  23. Nardelli M (1995) J Appl Cryst 28:659

    Article  CAS  Google Scholar 

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Acknowledgments

We are grateful to Institute Instrumentation Centre (IIC), Indian Institute of Technology, Roorkee for magnetic studies. One of the Authors (Rajnikant) acknowledges the Department of Science & Technology for single crystal X-ray diffractometer sanctioned as a National Facility under research project No. SR/S2/CMP-47/2003.

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Authors and Affiliations

  1. Department of Chemistry, University of Jammu, Jammu Tawi, 180 006, India

    Sanjay Kapoor & Renu Sachar

  2. X-ray Crystallography Laboratory, Post Graduate Department of Physics, University of Jammu, Jammu Tawi, 180 006, India

    Kuldeep Singh, Vivek K. Gupta & Verma Rajnikant

Authors
  1. Sanjay Kapoor
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  2. Renu Sachar
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  3. Kuldeep Singh
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  4. Vivek K. Gupta
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  5. Verma Rajnikant
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Correspondence to Verma Rajnikant.

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Kapoor, S., Sachar, R., Singh, K. et al. Synthesis and Characterization of the Adducts of Bis(O-butyldithiocarbonato)nickel(II) with Substituted Heterocyclic Amines and X-ray Structure of Bis(O-butyldithiocarbonato)bis(4-cyanopyridine)nickel(II). J Chem Crystallogr 42, 222–226 (2012). https://doi.org/10.1007/s10870-011-0228-y

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