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Hydrothermal Synthesis, Crystal Structure and Properties of Two Organic Amine Templated Lanthanide Sulfates

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Abstract

Two new lanthanide sulfates [C6H14N2]2[Ln2(SO4)4(H2O)4][SO4]·6H2O (Ln = Pr 1, Nd 2) have been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction, IR and TGA. Single crystal X-ray diffraction illuminates that both 1 and 2 crystallize in orthorhombic crystal system, space group Pbna with cell dimensions: a = 10.1362(13) Å, b = 13.4782(17) Å, c = 25.565(3) Å, V = 3492.6(8) Å3, Z = 4 for 1; a = 10.1243(12) Å, b = 13.4438(16) Å, c = 25.550(3) Å, V = 3477.6(7) Å3, Z = 4 for 2. Structure analysis indicates that both 1 and 2 are layered structures and the sulfate ions as well as the organic templates reside among the layers. Magnetic property of compound 1 was investigated further.

Graphical Abstract

Two new lanthanide sulfates [C6H14N2]2[Ln2(SO4)4(H2O)4][SO4]·6H2O (Ln = Pr 1, Nd 2) are layered structures and the sulfate ions as well as the organic templates reside among the layers.

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Acknowledgments

We thank the National Natural Science Foundation of China (20971068) for financial support.

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Authors and Affiliations

  1. State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemistry and Chemical Engineering, Nanjing University of Technology, Nanjing, 210009, People’s Republic of China

    Jie Fu, Lei Zheng, Yan Yuan & Yan Xu

  2. State Key Laboratory of Coordination Chemistry, Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, People’s Republic of China

    You Song

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  1. Jie Fu
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  2. Lei Zheng
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  3. Yan Yuan
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  4. You Song
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  5. Yan Xu
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Correspondence to Yan Xu.

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Fu, J., Zheng, L., Yuan, Y. et al. Hydrothermal Synthesis, Crystal Structure and Properties of Two Organic Amine Templated Lanthanide Sulfates. J Chem Crystallogr 41, 1737–1741 (2011). https://doi.org/10.1007/s10870-011-0166-8

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  • DOI: https://doi.org/10.1007/s10870-011-0166-8

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