Abstract
Three new polymeric frameworks, [Ni(bbbm)(L1)2] n (1), [Ni(bbbm)(L2)2] n (2), and {[Co(bbbm)(L3)]·H2O} n (3) (bbbm = 1,4-bis(N-benzimidazolyl) butane, HL1 = 4-bromobenzoic acid, HL2 = 3-methylbenzoic acid, and H2L3 = glutaric acid) have been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction. Complex 1 features a one-dimensional (1D) linear chain structure bridged by bbbm ligands, which is further connected into a supramolecular double chain structure through intermolecular π–π stacking interactions. Complex 2 contains 1D zigzag chain, which is further arranged into a 2D supramolecular architecture by hydrogen bonding and π–π stacking interactions. In the structure of 3, there are infinite 1D zigzag Co(II)-bbbm chains linked together by L3 ligands to generate an undulated 2D (4,4) sheet, which is further connected by intermolecular π–π stacking interactions to form a 3D supramolecular network. Furthermore, thermal stability and luminescent property of 1–3 were investigated.
Graphical Abstract
Three new two/three-dimensional supramolecular complexes [Ni(bbbm)(L1)2] n (1), [Ni(bbbm)(L2)2] n (2), and {[Co(bbbm)(L3)]·H2O} n (3) [bbbm = 1,4-bis(N-benzimidazolyl) butane] have been synthesized from hydrothermal reaction of a metal salt with ligands: bbbm and one carboxylate ligand, 4-bromobenzoic acid (HL1), 3-methylbenzoic (HL2), and glutaric acid (H2L3).
Similar content being viewed by others
References
Dan-Hardi M, Serre C (2009) J Am Chem Soc 131:10857
Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O’Keeffe M, Yaghi OM (2002) Science 295:469
Zou RQ, Sakurai H, Han S, Zhong RQ, Xu Q (2007) J Am Chem Soc 129:8402
Dan M, Rao CNR (2006) Angew Chem Int Ed 45:281
Robin AY, Fromm KM (2006) Coord Chem Rev 250:2127
Kaneko W, Ohba M, Kitagawa S (2007) J Am Chem Soc 129:13706
Cheng L, Zhang WX, Ye BH, Lin JB, Chen XM (2007) Eur J Inorg Chem 18:2668
Zhu XD, Lu J, Li XJ, Gao SY, Li GL, Xiao FX, Cao R (2008) Cryst Growth Des 8:1897
Yoon JW, Jhung SH, Hwang YK, Humphrey SM, Wood PT, Chang JS (2007) Adv Mater 19:1830
Chae HK, Siberio DY, Kim J, Eddaoudi GY, Matzger MJ, Keeffe MO, Yaghi OM (2004) Nature 427:523
Kitagawa S, Uemura K (2005) Chem Soc Rev 34:109
Wang XL, Chen YQ, Zhang JX, Liu GC, Lin HY, Tian AX (2010) Z Anorg Allg Chem 636:830
Wang LS, Zhu L, Yin PC, Wei YG (2009) Inorg Chem 48:9222
Yang J, Ma JF, Liu YY, Ma JC, Batten SR (2007) Inorg Chem 46:6542
Zhou LJ, Wang YY, Zhou CH, Wang CJ, Shi QZ, Peng SM (2007) Cryst Growth Des 7:300
Hunger J, Krautscheid H, Sieler J (2009) Cryst Growth Des 9:4613
Yang HX, Meng XR, Liu Y, Hou HW, Fan YT, Shen XQ (2008) J Solid State Chem 181:2178
Chen JQ, Cai YP, Fang HC, Zhou ZY, Zhan XL, Zhao G, Zhang Z (2009) Cryst Growth Des 9:1605
Li SL, Lan YQ, Ma JC, Ma JF, Su ZM (2010) Cryst Growth Des 10:1161
Li LL, Yuan RX, Liu LL, Ren ZG, Zheng AX, Cheng HJ, Li HX, Lang JP (2010) Cryst Growth Des 10:1929
Niu YY, Zhang N, Hou HW, Zhu Y, Tang MS, Ng SW (2007) J Mol Struct 827:195
Fan J, Hanson BE (2005) Inorg Chem 44:6998
Chang Q, Meng XR, Song YL, Hou HW (2005) Inorg Chim Acta 358:2117
Xiao B, Han HY, Meng XR, Song YL, Fan YT, Hou HW, Zhu Y (2004) Inorg Chem Commun 7:378
She JB, Zhang GF, Dou YL (2006) Acta Crystallogr Sect E E62:o402
Sheldrick GM (1997) SHELXS-97, program for the solution of crystal structure. University of Göttingen, Göttingen
Sheldrick GM (1997) SHELXL-97, program for the refinement of crystal structure. University of Göttingen, Göttingen
Yang YT, Luo F, Che YX, Zheng JM (2008) Cryst Growth Des 8:3508
Wang XL, Bi YF, Lin HY, Liu GC (2007) Cryst Growth Des 7:1086
Pan ZR, Song Y, Jiao Y, Fang ZJ, Li YZ, Zheng HG (2008) Inorg Chem 47:5162
Liu GX, Huang YQ, Chu Q, Okamura T, Sun WY, Liang H, Ueyama N (2008) Cryst Growth Des 8:3233
Zhou DS, Wang FK, Yang SY, Xie ZX, Huang RB (2009) CrystEngComm 11:2548
Acknowledgments
Financial supports of this research by the NCET-09-0853, Talent-supporting Program Foundation of Liaoning Province (No. 2009R03) and Program Foundation of Liaoning Province Silicon Materials Engineering Technology Research Center (2009402007) are greatly acknowledged.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Wang, XL., Zhang, JX., Hou, LL. et al. Three New Complexes Based on a Flexible Bis(benzimidazole) Ligand and Rigid/Flexible Organic Carboxylates. J Chem Crystallogr 41, 1579–1585 (2011). https://doi.org/10.1007/s10870-011-0143-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10870-011-0143-2