Skip to main content
SpringerLink
Log in

Synthesis and Crystal Structure of (E)-1-(2,3-Dihydroxybenzlidene)-4,4-Dimethythiosemicarbazide

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The Schiff base C10H13N3O2S is monoclinic, having unit cell parameters a = 9.788(1) Å, b = 9.615(1) Å, c = 12.605(1) Å, β = 108.41(1)° and V = 1125.56(2) Å3 and belongs to P21/n space group. The molecule is almost planar. The two hydroxyl groups present on the phenyl ring are involved in intermolecular H-bonding, which results in the stacking of molecules in the anti-parallel fashion leading an interesting network of channels. Besides this C–H⋯π and π–π (edge to edge) interactions appear to provide stability to the crystal lattice.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. Cambell MJM (1975) Coord Chem Rev 15:279

    Article  Google Scholar 

  2. Padhye SB, Kauffman GB (1985) Coord Chem Rev 63:127

    Article  CAS  Google Scholar 

  3. Haiduo I, Silvestru C (1990) Coord Chem Rev 99:253

    Article  Google Scholar 

  4. West DX, Padye SB, Sonawane PB (1991) Struct Bond 76:1

    CAS  Google Scholar 

  5. Tion YP, Duan CY, Lu ZL, You XZ, Fun HK, Kandasamy S (1996) Polyhedron 15(13):2263

    Article  Google Scholar 

  6. Chattopadhyay D, Mazumdar SK, Banerjee T, Ghosh S, Mak TCW (1988) Acta Crystallogr C 44:1025

    Article  Google Scholar 

  7. Seena EB, Kurup MRP, Suresh E (2008) J Chem Crystallogr 38:93

    Article  CAS  Google Scholar 

  8. Jayasree S, Arvindakshan KK (1993) Transition Met Chem 18:85

    Article  CAS  Google Scholar 

  9. Bernstein J, Yale HL, Losee K, Holsing M, Martins J, Lott WA (1951) J Am Chem Soc 73:906

    Article  CAS  Google Scholar 

  10. Donovick R, Pansy F, Stryker G, Bernstein J (1950) J Bacteriol 59:667

    CAS  Google Scholar 

  11. Swesi AT, Farina Y, Kassim M, Weng S (2006) Acta Crystallogr E 62:o5457

    Article  Google Scholar 

  12. Siemens XSCANS (1994) X-ray single crystal analysis system, version 2.1. Siemens Analytical X-Ray Instruments Inc., Madison

    Google Scholar 

  13. Altomare A, Cascarano G, Giacovazzo C, Guagliardi A (1993) J Appl Crystallogr 26:343

    Article  Google Scholar 

  14. Sheldrick GM (1997) SHELX97. University of Göttingen, Göttingen

    Google Scholar 

  15. Farrugia LJ (1999) J Appl Crystallogr 32:837

    Article  CAS  Google Scholar 

  16. Seena EB, Bessy Raj BN, Kurup MRP, Suresh E (2006) J Chem Crystallogr 36:189

    Article  CAS  Google Scholar 

  17. Tan KW, Farina Y, Hee C, Maah MJ, Weng S (2008) Acta Crystallogr E 64:o1073

    Article  Google Scholar 

Download references

Acknowledgment

A. P. S. Pannu is grateful to the University Grants Commission for research fellowship.

Author information

Authors and Affiliations

  1. Department of Chemistry, Guru Nanak Dev University, Amritsar, 143005, India

    Ajay Pal Singh Pannu & Maninder Singh Hundal

Authors
  1. Ajay Pal Singh Pannu
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Maninder Singh Hundal
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Maninder Singh Hundal.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Pannu, A.P.S., Hundal, M.S. Synthesis and Crystal Structure of (E)-1-(2,3-Dihydroxybenzlidene)-4,4-Dimethythiosemicarbazide. J Chem Crystallogr 41, 1447–1450 (2011). https://doi.org/10.1007/s10870-011-0119-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-011-0119-2

Keywords

Search

Navigation