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Hydrothermal Synthesis and Electrochemical Properties of Complex Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-κN2)picolinato-κ2N,O] iron(II) tetrahydrate

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Abstract

The title complex has been synthesized by 6-(3, 5-dimethyl-1H-pyrazol-1-yl) picolinic acid (DPPA) in the mixed solvent of water and methanol. It crystallizes in the triclinic system, space group P-1 with a = 0.98383 (14), b = 1.08094 (18), c = 1.2774 (2) nm, α = 71.0260 (10), β = 74.5130 (10), γ = 84.350 (2)°, C22H28FeN6O8, M r  = 560.35, V = 1.2379 (3) nm3, D c  = 1.503 g/cm3, Z = 2, F(000) = 584, μ(MoKα) = 0.669 mm−1, R = 0.0814 and wR = 0.1624. Structural analysis shows that the iron atom is coordinated with two oxygen atoms from the carboxyl group of the ligand together with four nitrogen atoms from the pyridine rings and pyrazole rings. The spectroscopy and electrochemical properties of the complex has also been described.

Graphical Abstract

A novel complex, Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-κN2)picolinato-κ2N,O] iron(II) tetrahydrate containing the ligand of 6-(3, 5-dimethyl-1H-pyrazol-1-yl)picolinic acid, was obtained and its structure was determined by single crystal X-ray diffraction. The spectrum and electrochemical properties of the complex have been investigated

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References

  1. Jones JC (1998) Chem Soc Rev 27:289

    Article  CAS  Google Scholar 

  2. Ye BH, Tong ML, Chen XM (2005) Coord Chem Rev 249:545

    Article  CAS  Google Scholar 

  3. Bala R, Sharma RP, Sharma U, Burrows AD, Cassar K (2007) J Mol Struct 832:156

    Article  CAS  Google Scholar 

  4. Ebrahimi A, Habibi Khorassani SM, Delarami H (2009) Chem Phys 365:18

    Article  CAS  Google Scholar 

  5. Godoy Netto AV, Frema RCG, Mauro AE, de Almeida ET, Santana AM, de Souza J Jr, Santos RHA (2003) Inorg Chim Acta 350:252

    Article  CAS  Google Scholar 

  6. Bala R, Sharma RP, Bond AD (2007) J Mol Struct 830:198

    Article  CAS  Google Scholar 

  7. Mukherjee R (2000) Coord Chem Rev 203:151

    Article  CAS  Google Scholar 

  8. Gupta R, Mukherjee R (2001) Polyhedron 20:2545

    Article  CAS  Google Scholar 

  9. Khaled RA, Abdellatif, Morshed AC, Ying D, Edward EK (2008) Polyhedron 16:6528

    Google Scholar 

  10. Trofimenko S (1986) Prog Inorg Chem 34:115

    Article  CAS  Google Scholar 

  11. Trofimenko S (1972) Chem Rev 72:497

    Article  CAS  Google Scholar 

  12. Martinez AP, Fabra MJ, García MP, Lahoz FJ, Oro LA, Teat SJ (2005) Inorg Chim Acta 358:1635

    Article  CAS  Google Scholar 

  13. Monica GL, Ardizzoia GA (1997) Prog Inorg Chem 46:151

    Article  Google Scholar 

  14. Trofimenko S (1993) Chem Rev 93:943

    Article  CAS  Google Scholar 

  15. Woodward JD, Backov RV, Abboud KA, Talham DR (2006) Polyhedron 25:2605

    Article  CAS  Google Scholar 

  16. Rao CNR, Natarajan S, Vaidhyanathan R (2004) Angew Chem Int Ed 43:1466

    Article  CAS  Google Scholar 

  17. Ye BH, Sun AP, Wu TF, Weng YQ, Chen XM (2005) Eur J Inorg Chem 7:1230

    Article  Google Scholar 

  18. Ye BH, Ding BB, Weng YQ, Chen XM (2004) Inorg Chem 43:6866

    Article  CAS  Google Scholar 

  19. Atwood JL, Barbour LJ, Ness TJ, Raston CL, Raston L (2001) J Am Chem Soc 123:7192

    Article  CAS  Google Scholar 

  20. Barbour LJ, Orr GW, Atwood JL (1998) Nature 393:671

    Article  CAS  Google Scholar 

  21. Yang J, Ma JF, Liu YY, Ma JC, Jia HQ, Hu NH (2006) Eur J Inorg Chem 45:1208

    Article  Google Scholar 

  22. Ma BQ, Sun HL, Gao S (2004) Angew Chem Int Ed 43:1374

    Article  CAS  Google Scholar 

  23. Severance RC, Ellsworth J, Smith MD, Kelley J, Peterson L Jr, zur Loye HC (2010) J Chem Crystallogr 40:1065

    Article  CAS  Google Scholar 

  24. Guan YF, Zhou AJ, Wang DY, Wang J, Dong W (2009) J Mol Struct 938:150

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors thank the National Natural Science Foundation of China (20761002), P.R. China, the Natural Science Foundation of GuangXi (0832080), and Innovation Project of Guangxi University for Nationalities (Nos. gxun-chx2010080).

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Authors and Affiliations

  1. College of Chemistry and Ecological Engineering, Guangxi University for Nationalities, Nanning, 530006, People’s Republic of China

    Ji-Chang Zhuang, Xian-Hong Yin, Qiao-Lan Wu, Zhi-Rong Luo & Yue Zhuang

  2. Department of Food and Chemistry, ZhongShan Technical Institute, ZhongShan, 528400, People’s Republic of China

    Fei-Long Hu

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  1. Ji-Chang Zhuang
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Correspondence to Xian-Hong Yin.

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Zhuang, JC., Hu, FL., Yin, XH. et al. Hydrothermal Synthesis and Electrochemical Properties of Complex Bis[6-(3,5-dimethyl-1H-pyrazol-1-yl-κN2)picolinato-κ2N,O] iron(II) tetrahydrate. J Chem Crystallogr 41, 787–790 (2011). https://doi.org/10.1007/s10870-010-9976-3

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