Abstract
The coordination complex Cu(ppca′)2(H2O)2 (1) was synthesized hydrothermally using the ligand 3,4′-bipyridine-6-carboxylic acid (ppca′). Complex 1 consists of pseudo-octahedral copper (II) units hydrogen bonded into a three-dimensional network that crystallizes in the monoclinic P21/n space group. In complex 1, a = 5.3429(4) Å, b = 29.343(2) Å, c = 6.7940(5) Å, and β = 110.635(2)°.
Graphical Abstract
The coordination complex Cu(ppca′)2(H2O)2 (1) was synthesized hydrothermally using the ligand 3,4′-bipyridine-6-carboxylic acid (ppca′). The coordination sphere about the copper (II) ion in the complex Cu(ppca′)2(H2O)2 (1). Displacement ellipsoids are drawn at the 50% probability level.
= nitrogen,
= copper (II),
= oxygen,
= carbon, and
= hydrogen.
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Financial support from the National Science Foundation through Grant CHE-0714439 and Grant CHE-0714555 is gratefully acknowledged.
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Severance, R.C., Ellsworth, J., Smith, M.D. et al. Synthesis and Crystal Structure of the Coordination Complex Cu(ppca′)2(H2O)2 (ppca′ = 3,4′-Bipyridine-6-Carboxylic Acid). J Chem Crystallogr 40, 1065–1068 (2010). https://doi.org/10.1007/s10870-010-9795-6
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DOI: https://doi.org/10.1007/s10870-010-9795-6