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Synthesis and Structure of a One-Dimensional Copper(II)–Potassium(I) Complex of (S)-2-Hydroxy-3-Phenylpropanoic acid

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Abstract

Evaporation of the mixture solution of Cu(ClO4)2·6H2O, KOH and (S)-2-hydroxy-3-phenylpropanoic acid affords a Cu(II)–K(I) coordination compound 1. Single-crystal X-ray diffraction analysis reveals that 1 is a one-dimensional comb-like coordination polymer in the P212121 space group with crystal cell parameters a = 10.989(2) Å, b = 15.939(3) Å, c = 22.511(5) Å, V = 3943(1) Å3 and Z = 4.

Graphical Abstract

Evaporation of the mixture solution of Cu(ClO4)2·16H2O, KOH and (S)-2-hydroxy-3-phenylpropanoic acid affords a Cu(II)–K(I) coordination compound 1 with a one-dimensional comb-like structure.

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (20951003), and the Science and Technology Fund (KJ2009374) from SEU.

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Authors and Affiliations

  1. Ordered Matter Science Research Center, Southeast University, Nanjing, 211189, People’s Republic of China

    Rui-Jun Xu, Yan Cui & Wen Zhang

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  1. Rui-Jun Xu
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  2. Yan Cui
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  3. Wen Zhang
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Correspondence to Wen Zhang.

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Xu, RJ., Cui, Y. & Zhang, W. Synthesis and Structure of a One-Dimensional Copper(II)–Potassium(I) Complex of (S)-2-Hydroxy-3-Phenylpropanoic acid. J Chem Crystallogr 41, 779–782 (2011). https://doi.org/10.1007/s10870-010-9973-6

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  • DOI: https://doi.org/10.1007/s10870-010-9973-6

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