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Solvothermal Syntheses and Crystal Structures of Neodymium Thiostannates [Nd(dien)3]2[(Sn2S6)Cl2] and [Nd(dien)3]2[(Sn2S6)(SH)2]

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Abstract

Two neodymium thiostannates [Nd(dien)3]2[(Sn2S6)Cl2] (1) and [Nd(dien)3]2[(Sn2S6)(SH)2] (2) (dien = diethylenetriamine) were synthesized by the reaction of tin and sulfur in the presence of NdCl3 and Nd2O3, respectively under solvothermal conditions. Compounds 1 and 2 crystallize in monoclinic space group P21/n. Crystallographic data for 1: a = 11.6722(16), b = 15.119(2), c = 14.1566(19) Å, β = 96.213(3)°, V = 2483.6(6) Å3, Z = 4. For 2: a = 11.7190(14), b = 15.2168(19), c = 14.2209(18) Å, β = 95.775(4)°, V = 2523.1(5) Å3, Z = 4. The nine-coordinate [Nd(trien)3]3+ complex cation formed in situ acts as the counter ion to the [Sn2S6]4− anion. The [Nd(dien)3]3+, [Sn2S6]4− and Cl– (or SH–) ions form a 3-dimensional network structure through the N–H···S and N–H···Cl hydrogen bonds.

Graphical Abstract

New lanthanide thiostannates [Nd(dien)3]2[(Sn2S6)Cl2] and [Nd(dien)3]2[(Sn2S6)(SH)2] with 3-dimensional H-bonding network structures were synthesized in diethylenetriamine (dien) under mild solvothermal conditions.

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Acknowledgments

This work was supported by the National Natural Science Foundation of P. R. China (No. 20771077), and the Key Laboratory of Organic Synthesis of Jiangsu Province, Suzhou University.

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Authors and Affiliations

  1. Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Box 174, Ren Ai Road, 215123, Suzhou, People’s Republic of China

    Xin-hua Lu, Jing-jing Liang, Jing Zhao, Yong Zhang & Ding-xian Jia

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  1. Xin-hua Lu
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  2. Jing-jing Liang
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  5. Ding-xian Jia
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Correspondence to Ding-xian Jia.

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Lu, Xh., Liang, Jj., Zhao, J. et al. Solvothermal Syntheses and Crystal Structures of Neodymium Thiostannates [Nd(dien)3]2[(Sn2S6)Cl2] and [Nd(dien)3]2[(Sn2S6)(SH)2]. J Chem Crystallogr 41, 557–562 (2011). https://doi.org/10.1007/s10870-010-9921-5

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  • DOI: https://doi.org/10.1007/s10870-010-9921-5

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