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Synthesis, Characterization and Fluorescent Property of Two Mixed Ligand Coordination Polymers Constructed from 4-Cyclohexene-1,2-dicarboxylate and Nitrogen-Containing Ligands

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Abstract

Two new coordination polymers [Cd(1,2′-cy)(btx)0.5H2O]n 1 and {[Ni(1,2-cy)(2,2′-bipy)(H2O)2]·3H2O}n 2 (1,2′-cy=4-cyclohexene-1,2-dicarboxylate, btx=1,4-bis(triazol-1-ylmethyl)benzene, 2,2′-bipy=2,2′-bipyridine) had been synthesized. Their structures were characterized by elemental analysis, IR, TG and X-ray single-crystal diffraction analysis. Crystal data for complex 1: Triclinic, space group P-1, a = 6.4303(13) Å, b = 10.399(2) Å, c = 11.713(2), α = 83.04(3)°, β = 81.87(3)°, γ = 83.84(3)°, and Z = 2. For complex 2: Orthorhombic, space group Pbcn, a = 15.613(3) Å, b = 13.970(3) Å, c = 21.290(4) Å, and Z = 4. Complex 1 exhibits an interesting two-dimensional wavelike covalent layer structure. When Ni salt was replaced by Cd salt, and reacts with 1,2′-cy and 2,2′-bipy, one-dimensional chain-like complex 2 was obtained. Furthermore, the fluorescent property of complex 1 was reported.

Graphical Abstract

Two new coordination polymers [Cd(1,2′-cy)(btx)0.5H2O]n 1 and {[Ni(1,2-cy)(2,2′-bipy)(H2O)2]·3H2O}n 2 (1,2′-cy=4-cyclohexene-1,2-dicarboxylate, btx=1,4-bis(triazol-1-ylmethyl)benzene, 2,2′-bipy=2,2′-bipyridine) had been synthesized. Their structures were characterized by elemental analysis, IR, TG and X-ray single-crystal diffraction analysis. Crystal data for complex 1: Triclinic, space group P-1, a = 6.4303(13) Å, b = 10.399(2) Å, c = 11.713(2), α = 83.04(3)°, β = 81.87(3)°, γ = 83.84(3)°, and Z = 2. For complex 2: Orthorhombic, space group Pbcn, a = 15.613(3) Å, b = 13.970(3) Å, c = 21.290(4) Å, and Z = 4. Complex 1 exhibits an interesting two-dimensional wavelike covalent layer structure. When Ni salt was replaced by Cd salt, and reacts with 1,2′-cy and 2,2′-bipy, one-dimensional chain-like complex 2 was obtained. Furthermore, the fluorescent property of complex 1 was reported.

The interesting two-dimensional wavelike covalent layer structure of complex 1

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Acknowledgments

We gratefully acknowledge financial support from the China Postdoctoral Science Foundation (20100470073), Fundamental Research Funds for the Central Universities (N09035002), Open Project of State Key Laboratory for Supramolecular Structure and Materials, China (SKLSSM 201002), and the Postdoctoral Station Foundation of Northeast Normal University.

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Authors and Affiliations

  1. Department of Chemistry, College of Science, Northeast University, Shenyang, 110004, People’s Republic of China

    Xin-Xin Xu, Xiao-Xia Liu, Xiao-Guang Sang, Xia Zhang & Ting Sun

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  1. Xin-Xin Xu
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  2. Xiao-Xia Liu
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  4. Xia Zhang
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Correspondence to Xiao-Xia Liu.

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Xu, XX., Liu, XX., Sang, XG. et al. Synthesis, Characterization and Fluorescent Property of Two Mixed Ligand Coordination Polymers Constructed from 4-Cyclohexene-1,2-dicarboxylate and Nitrogen-Containing Ligands. J Chem Crystallogr 41, 453–457 (2011). https://doi.org/10.1007/s10870-010-9900-x

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