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Hydrothermal Syntheses and Structures of Lanthanide Coordination Polymers with 5-Aminoisophthalate and 1,10-Phenthroline

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Abstract

Two new lanthanide coordination polymers, [Ln2(APA)2(HAPA)2(phen)2] n [Ln = Pr (1), Eu (2); H2APA = 5-aminoisophthalic acid, phen = 1,10-Phenanthroline] have been synthesized by hydrothermal method, and characterized by single crystal X-ray diffraction, elemental analysis and IR spectra. Crystallographic data show that complexes 1 and 2 both crystallize in a triclinic system, space group \( P\bar{1} \). The titled compounds own 2-D herringbone structures which are further constructed to form 3-D supramolecular structures by N–H···O and O–H···O hydrogen bondings. The thermogravimetric analyses were carried out to examine the thermal stability of the title complexes. And the photoluminescence property of 2 was investigated.

Index Abstract

In the title complexes 5-aminoisophthalic acids link the lanthanide ions to 2-D herringbone structures which are further constructed to form 3-D supramolecular structures. Two 3-D lanthanide supramolecular coordination polymers with high thermal stability have been synthesized by hydrothermal method.

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Acknowledgments

This work is supported by National Natural Science Foundation of China (20961007) and Nanchang Hangkong University Fund (No. EA200702195).

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Authors and Affiliations

  1. College of Environment and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063, People’s Republic of China

    Chong-Bo Liu, Xing-Hua Tang, Yuan Ding, Hong-Ying Shu & Zhi-Min Huang

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  1. Chong-Bo Liu
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  2. Xing-Hua Tang
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  3. Yuan Ding
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  4. Hong-Ying Shu
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  5. Zhi-Min Huang
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Correspondence to Chong-Bo Liu.

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Liu, CB., Tang, XH., Ding, Y. et al. Hydrothermal Syntheses and Structures of Lanthanide Coordination Polymers with 5-Aminoisophthalate and 1,10-Phenthroline. J Chem Crystallogr 41, 198–203 (2011). https://doi.org/10.1007/s10870-010-9863-y

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