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Sandwich-Type Manganese-Substituted Polyoxometalate, [(α-B-ZnW9O34)2W2Mn2(H2O)2]8−

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Abstract

The novel dimeric manganese-substituted polyoxotungstate Na10[(α-B-ZnW9O34)2W2Mn2(H2O)2](OH)2·34H2O (1) has been designed and synthesized from the hydrothermal reaction of Na2WO4·2H2O, MnCl2·4H2O, and ZnCl2 in a Teflon-lined stainless steel autoclave at 140°. X-ray diffraction analysis results reveal that compound (1) crystallizes in the monoclinic system, space group P2(1)/n, with a = 13.0901(3) Å, b = 17.8242(4) Å, c = 21.2401(5) Å, β = 93.6380(10)°, Z = 1, V = 4945.8(2) Å3, F(000) = 5244, Dc = 3.974 g/cm−3, μ(Mo-Kα) = 2.4037 cm−1, λ(Mo-Kα) = 0.71073 Å. The structure was refined to R = 0.0631 and wR = 0.1532. The polyoxoanion of [(α-B-ZnW9O34)2W2Mn2(H2O)2]8− consist of two Keggin lacunary α-B-ZnW9O34 12− moieties linked via a rhomblike W2Mn2O16 group leading to a sandwich-type structure.

Graphical Abstract

The new dimeric polyoxotungstate Na10[(α-B-ZnW9O34)2W2Mn2(H2O)2](OH)2·34H2O (1) has been designed and synthesized from the hydrothermal reaction of Na2WO4·2H2O, MnCl2·4H2O, and ZnCl2 in a Teflon-lined stainless steel autoclave at 140°. X-ray diffraction analysis results reveal that the polyoxoanion of [(α-B-ZnW9O34)2W2Mn2(H2O)2]8− consists of two Keggin lacunary α-B-ZnW9O34 12− moieties linked via a rhomblike W2Mn2O16 group leading to a sandwich-type structure.

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References

  1. Pope MT, Müller A (1991) Angew Chem Int Ed Engl 30:34

    Article  Google Scholar 

  2. Hill CL (1998) Chem Rev Polyoxometalates 98

  3. Pope MT, Müller A (1994) Polyoxometalates: from platonic solids to anit-retroviral activity. Kluwer Academic Publishers, Dordrecht, The Netherlands

  4. Pope MT (1983) Heteropoly and isopoly oxometalates. Springer, New York

  5. Wu CD, Lu CZ, Zhuang HH, Huang JS (2002) J Am Chem Soc 124:3836

    Article  CAS  Google Scholar 

  6. Zhang SW, Wei YG, Yu Q, Shao MC, Tang YQ (1997) J Am Chem Soc 119:6440

    Article  CAS  Google Scholar 

  7. Long DL, Abbas H, Köerler P, Cronin L (2005) Angew Chem Int Ed 44:3415

    Article  CAS  Google Scholar 

  8. Richardt PJS, Gable RW, Bond AM, Wedd AG (2001) Inorg Chem 40:703

    Article  CAS  Google Scholar 

  9. Rüther T, Hultgren VM, Timko BP, Bond AM, Jackson WR, Wedd AG (2003) J Am Chem Soc 125:10133

    Article  Google Scholar 

  10. Kim WB, Voitl T, Rodriguez-Rivera GJ, Evans ST, Dumesic JA (2005) Angew Chem Int Ed 44:778

    Article  CAS  Google Scholar 

  11. Yamase T (1998) Chem Rev 98:307

    Article  CAS  Google Scholar 

  12. Coronado E, Gómez-Garcia CJ (1998) Chem Rev 98:273

    Article  CAS  Google Scholar 

  13. Ben-Daniel R, Neumann R (2003) Angew Chem Int Ed 42:92

    Article  CAS  Google Scholar 

  14. López X, Bo C, Poblet JM (2002) J Am Chem Soc 124:12574

    Article  Google Scholar 

  15. Kortz U, Mbomekalle IM, Keita B, Nadjo L, Berthet P (2002) Inorg Chem 41:6412

    Article  CAS  Google Scholar 

  16. Aguey-Zinsou KF, Bernhardt PV, Kappler U, Mcewan AG (2003) J Am Chem Soc 125:530

    Article  CAS  Google Scholar 

  17. Judd DA, Nettles JH, Nevins N, Snyder JP, Liotta DC, Tang J, Ermolieff J, Schinazi RF, Hill CL (2001) J Am Chem Soc 123:886

    Article  CAS  Google Scholar 

  18. Nomiya K, Torii H, Hasegawa T, Nemoto Y, Nomura K, Hashino K, Uchida M, Kato Y, Shimizu K, da MO (2001) J Inorg Biochem 86(4):657

  19. Bartis J, Dankova M, Lessmann JJ, Luo QH, Horrocks WD Jr, Francesconi LC (1999) Inorg Chem 38:1042

    Article  CAS  Google Scholar 

  20. Haraguchi N, Okaue Y, Isobe T, Matsuda Y (1994) Inorg Chem 33:1015

    Article  CAS  Google Scholar 

  21. Ciabrini J-P, Contant R (1993) J Chem Res Miniprint 2720

  22. Sadakane M, Dickman MH, Pope MT (2001) Inorg Chem 40:2715

    Article  CAS  Google Scholar 

  23. Weakley TJR, Evans HT, Showell JS, Tourné GF, Tourné CM (1973) J Chem Soc Chem Commun 139

  24. Finke RG, Droege M, Hutchinson JR, Gansow O (1981) J Am Chem Soc 103:1587

    Article  CAS  Google Scholar 

  25. Finke RG, Droege MW (1983) Inorg Chem 22:1006

    Article  CAS  Google Scholar 

  26. Evans HT, Tourné CM, Tourné GF, Weakley TJR (1986) J Chem Soc Dalton Trans 2699

  27. Finke RG, Droege MW, Domaille PJ (1987) Inorg Chem 26:3886

    Article  CAS  Google Scholar 

  28. Wasfi SH, Rheingold AL, Kokoszka GF, Goldstein AS (1987) Inorg Chem 26:2934

    Article  CAS  Google Scholar 

  29. Weakley TJR, Finke RG (1990) Inorg Chem 29:1235

    Article  CAS  Google Scholar 

  30. Zhang XY, Jameson GB, O’Connor CJ, Pope MT (1996) Polyhedron 15:917

    Article  CAS  Google Scholar 

  31. Zhang X, Chen Q, Duncan DC, Campana C, Hill CL (1997) Inorg Chem 36:4208

    Article  CAS  Google Scholar 

  32. Zhang X, Chen Q, Duncan DC, Lachicotte RJ, Hill CL (1997) Inorg Chem 36:4381

    Article  CAS  Google Scholar 

  33. Clemente-Juan JM, Coronado E, Galän-Mascarös JR, Gömez-Garcöa CJ (1999) Inorg Chem 38:55

    Article  CAS  Google Scholar 

  34. Bi LH, Wang EB, Peng J, Huang RD, Xu L, Hu CW (2000) Inorg Chem 39:671

    Article  CAS  Google Scholar 

  35. Bi LH, Huang RD, Peng J, Wang EB, Wang YH, Hu CW (2004) J Chem Soc Dalton Trans 121

  36. Kortz U, Isber S, Dickman MH, Ravot D (2000) Inorg Chem 39:2915

    Article  CAS  Google Scholar 

  37. Limanski EM, Piepenbrink M, Droste E, Burgemeister K, Krebs B (2002) J Clust Sci 13:369

    Article  CAS  Google Scholar 

  38. Zhang X, Anderson TM, Chen Q, Hill CL (2001) Inorg Chem 40:418

    Article  CAS  Google Scholar 

  39. Anderson TM, Zhang X, Hardcastle KI, Hill CL (2002) Inorg Chem 41:2477

    Article  CAS  Google Scholar 

  40. Anderson TM, Hardcastle KI, Okun N, Hill CL (2001) Inorg Chem 40:6418

    Article  CAS  Google Scholar 

  41. Ruhlmann L, Canny J, Contant R, Thouvenot R (2002) Inorg Chem 41:3811

    Article  CAS  Google Scholar 

  42. Meng L, Zhan XP, Wang M, Liu JF (2001) Polyhedron 20:881

    Article  CAS  Google Scholar 

  43. Craciun C, David L (2001) J Alloys Compd 323:743

    Article  Google Scholar 

  44. Knoth WH, Domaille PJ, Harlow RL (1986) Inorg Chem 25:1577

    Article  CAS  Google Scholar 

  45. Tourné CM, Tourné GF, Zonnevijlle F (1991) J Chem Soc Dalton Trans 143

  46. Neumann R, Khenkin AM (1995) Inorg Chem 34:5753

    Article  CAS  Google Scholar 

  47. Bi L-H, Reicke M, Kortz U, Keita B, Nadjo L, Clark RJ (2004) Inorg Chem 43:3915

    Article  CAS  Google Scholar 

  48. Bi LH, Kortz U, Keita B, Nadjo L, Borrmann H (2004) Inorganic Chem 43:8367

    Article  CAS  Google Scholar 

  49. Kortz U, Al-Kassem NK, Savelieff MG, Al Kadi NA, Sadakane M (2001) Inorg Chem 40:4742

  50. Mialane P, Marrot J, Mallard A, Hervé G (2002) Inorg Chim Acta 328:81

    Article  CAS  Google Scholar 

  51. Lefebvre F, Leyrie M, Hervé G, Sanchez C, Livage J (1983) Inorg Chim Acta 73:173

    Article  CAS  Google Scholar 

  52. Kortz U, Holzapfel C, Reicke M (2003) J Mol Struct 656:93

    Article  CAS  Google Scholar 

  53. Jeannin Y, Martin-Frère J (1981) J Am Chem Soc 103:1664

    Article  CAS  Google Scholar 

  54. Keggin JF (1933) Nature (London) 131:908

    Article  CAS  Google Scholar 

  55. Brown GM, Noe-Spirlet MR, Busing WR, Levy HA (1977) Acta Crystallogr Sect B 33:1038

    Article  Google Scholar 

  56. Strandberg R (1977) Acta Crystallogr Sect B 33:3090

    Article  Google Scholar 

  57. Weakley TJR (1997) Acta Crystallogr Sect C 53, IUC9700025

  58. Finke R, Weakley TJR (1994) Chem Crystallogr 24:123

    Article  CAS  Google Scholar 

  59. Xin FB, Pope MT (1996) J Am Chem Soc 118:7731

    Article  CAS  Google Scholar 

  60. Finke RG, Rapko B, Weakley TJR (1989) Inorg Chem 28:1573

    Article  CAS  Google Scholar 

  61. Massart R, Contant R, Fruchart JM, Ciabrini JP, Fournier M (1977) Inorg Chem 16:2916

    Article  CAS  Google Scholar 

  62. Mccarron EM, Whitney JF, Chase DB (1984) Inorg Chem 23:3275

    Article  CAS  Google Scholar 

  63. Brese NE, O’Keeffe M (1991) Acta Crystallogr Sect B 47:192

    Article  Google Scholar 

  64. Sheldrick GM (1997) SHELXTL-97: program for refinement of crystal structures. University of Göttingen: Göttingen, Germany

  65. Sheldrick GM (2001) SADABS. University of Goöttingen, Germany

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Acknowledgements

The financial supports from NSFC (Grant No. 20501011) and Liaocheng University (31801). In particularly, we thank Professor Jianmin Dou for his help.

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Authors and Affiliations

  1. Department of Chemistry, Liaocheng University, Liaocheng, 252000, China

    Ying Liu, Jianmin Dou, Daqi Wang, Xianxi Zhang, Dacheng Li & Yingchun Jia

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  1. Ying Liu
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  2. Jianmin Dou
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  3. Daqi Wang
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  4. Xianxi Zhang
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Correspondence to Ying Liu.

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Liu, Y., Dou, J., Wang, D. et al. Sandwich-Type Manganese-Substituted Polyoxometalate, [(α-B-ZnW9O34)2W2Mn2(H2O)2]8− . J Chem Crystallogr 41, 186–191 (2011). https://doi.org/10.1007/s10870-010-9861-0

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