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Novel Assembly of a Cyanide-Bridged Copper(II)–Nickel(II) Binuclear Complex with a Copper(II) Macrocyclic Ligand

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Abstract

A mononuclear fragment [Cu(L)Cl]ClO4 (1) and a cyano-bridged CuII–NiII binuclear complex [CuL][Ni(CN)4]·0.25H2O (2) (L = 1,3,6,8,11,14-hexaazatricyclo[12.2.1.18,11]-octadecane), have been prepared and characterized. X-ray single crystal analyses indicate that the both complexes crystallize in the monoclinic crystalline system. The complex of 1 in P1n1 space group with unit cell constants a = 6.1176(6) Å, b = 11.9147(10) Å, c = 12.2041(12) Å, β = 98.816(5)° and 2 in the P21/n space group with unit cell constants a = 8.1419(13) Å, b = 14.695(2) Å, c = 16.863(3) Å, β = 98.375(2)° have been revealed. The complex 2 assumes a binuclear structure in which the nickel(II) ion is in a square planar environment and the copper(II) is in a square-prism geometry environment.

Graphical Abstract

A novel CuII–NiII bimetallic assembly constructed from Cu macrocyclic ligand and [Ni(CN)4]2− anion.

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Acknowledgement

This project was supported by the National Natural Science Foundation of China (Nos. 20631030, 20471031) and National Basic Research Program of China (973 Program, 2007CB815305).

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Authors and Affiliations

  1. Department of Application Chemistry, College of Science, Tianjin University of Commerce, Tianjin, 300134, People’s Republic of China

    Shu-Lin Ma & Shi Ren

  2. Department of Chemistry, Nankai University, Tianjin, 300071, People’s Republic of China

    Yue Ma, Shi-Ping Yan & Dai-Zheng Liao

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  1. Shu-Lin Ma
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  2. Shi Ren
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  4. Shi-Ping Yan
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Correspondence to Shu-Lin Ma or Dai-Zheng Liao.

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Ma, SL., Ren, S., Ma, Y. et al. Novel Assembly of a Cyanide-Bridged Copper(II)–Nickel(II) Binuclear Complex with a Copper(II) Macrocyclic Ligand. J Chem Crystallogr 40, 1011–1015 (2010). https://doi.org/10.1007/s10870-010-9786-7

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