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Unusual Polynuclear Copper(II) Complexes with a Schiff-Base Ligand Containing Pyridyl and 1,2,4-Triazolyl Rings

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Abstract

The reaction between Cu(NO3)2 and Schiff-base ligand 4-(pyridin-2-yl)methyleneamino-1,2,4-triazole (L) in water due to hydrolysis process results in the formation of new ligand 4-[bis(pyridin-2-yl-methanol)]amino-1,2,4-triazole (H2L1) and 4-amino-4H-1,2,4-triazole (L2). Slow diffusion of methanol or ethanol vapors into the reaction solution leads to the growth of single crystals of the 12-nuclear complex [Cu12(L1)4(L2)6(NO3)6(MeOH)2(H2O)6](NO3)10·3MeOH·11H2O (1) with an unusual cyclic metal core or 1D coordination polymer {[Cu3L1(L2)2(NO3)2(H2O)2](NO3)2·1.5H2O}n (2), respectively. According to the X-ray diffraction data, both structures are constructed from similarly formed units, where three copper atoms are linked by one [L1]2− ligand and two amino-1,2,4-triazolyl fragments. Magnetic behaviour of compound 2 indicates the presence of antiferromagnetic-type exchange coupling between CuII ions in the trinuclear unit {Cu1–Cu2–Cu3} (J12 = − 149 cm−1, J23 = –175 cm−1, zJ = − 0.7 cm−1).

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Acknowledgements

This study was supported by IGIC RAS state assignment. Single crystal and powder X-ray analyses, IR spectroscopy, CHN analysis, and magnetic measurements were performed at the Shared Facility Center at the Kurnakov Institute (IGIC RAS).

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Authors and Affiliations

  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninsky prosp. 31, Moscow, Russian Federation, 119991

    Evgeniya S. Bazhina, Anna A. Bovkunova, Nikolay N. Efimov, Mikhail A. Kiskin & Igor L. Eremenko

  2. Department of Chemistry, Moscow State University, Leninskie Gory 1/3, Moscow, Russian Federation, 119991

    Alexey V. Medved’ko

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  1. Evgeniya S. Bazhina
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  2. Anna A. Bovkunova
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Bazhina, E.S., Bovkunova, A.A., Medved’ko, A.V. et al. Unusual Polynuclear Copper(II) Complexes with a Schiff-Base Ligand Containing Pyridyl and 1,2,4-Triazolyl Rings. J Clust Sci 30, 1267–1275 (2019). https://doi.org/10.1007/s10876-019-01575-y

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