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Synthesis and Crystal Structure of 2D Supramolecular Compound [Co(phth)(phen) (H2O)3]·H2O

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Abstract

A 2D supramolecular compound [Co(phth)(phen) (H2O)3]·H2O has been synthysized by the reactions of Co(NO3)2·6H2O, 1, 10-phenanthroline(phen) and phthalate acid(H2phth) in NaOH solution with pH 7.0.The complex has been characterized by elemental analysis, IR, and single-crystal X-ray diffraction analysis which shows it belongs the monoclinic space group P2(1)/n, a = 7.571(2) Å, b = 13.737(3) Å, c = 20.015(4) Å, β = 95.56(1)°. V = 2071.9(8) Å3, Mr = 475.31, Dc = 1.524 g/cm−3, Z = 4, F(000) = 980, μ(MoKa) = 0.879 mm−1. The final R1 and wR2 are 0.0348 and 0.0711, respectively. The cobalt(II) ion is six-coordinated in a distorted octahedron to form a unit. Every unit is connected by hydrogen bonds forming 1D chain and 2D supramolecular network by π–π stacking interaction between adjoining chains.

Graphical Abstract

The molecular structure of the title complex.

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Acknowledgments

This work was supported by the Education Committee National Science Foundation of Hunan province (No. 02C464) and by Hunan University of Science and Technology National Science Foundation (No. G30506).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, 411201, Xiangtan, People’s Republic of China

    Li Tian, Lin Chen & Xin Zhang

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  1. Li Tian
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  2. Lin Chen
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  3. Xin Zhang
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Correspondence to Li Tian.

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Tian, L., Chen, L. & Zhang, X. Synthesis and Crystal Structure of 2D Supramolecular Compound [Co(phth)(phen) (H2O)3]·H2O. J Chem Crystallogr 40, 664–667 (2010). https://doi.org/10.1007/s10870-010-9716-8

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  • DOI: https://doi.org/10.1007/s10870-010-9716-8

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