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Two 3D Supramolecular Architectures Assembled With 1D or 2D Coordination Polymers by Cooperation of Coordination Bonds, Hydrogen Bonds and π···π Interactions

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Abstract

Two 3D supramolecular architectures, [Cu(tmbdc)(NH3)2] n , 1, (tmbdc = 2,3,5,6-tetramethylbenzenedicarboxylate), and {[Cu3(btc)2(NH3)6(H2O)]·2H2O} n , 2, (btc = 1,3,5-benzenetricarboxylate) have been assembled with 1D or 2D coordination polymers as supramolecular synthons. The geometry matching of the moieties is the key factor for the formation of the two supramolecular architectures by the cooperation of coordination bonds, hydrogen bonds and π···π interactions. Crystal data for 1: Formula CuC12H18N2O4, monoclinic, space group P21/c, a = 9.0134(5), b = 10.8785(5), c = 6.4702(3) Å, β = 91.679(1)°, V = 634.15(5) Å3, Z = 2, R 1 = 0.0251 and wR 2 = 0.0722. Crystal data for 2: Formula Cu3C18H30N6O15, monoclinic, space group C2/c, a = 13.9213(5), b = 17.1210(6), c = 12.5271(5) Å, β = 114.779(1)°, V = 2710.89(17) Å3, Z = 4, R 1 = 0.0245 and wR 2 = 0.0665. The positions and isotropic displacement parameters of all the hydrogen atoms are refined.

Graphical Abstract

The geometry matching of the moieties of 1D or 2D coordination polymers leads to the formation of two 3D supramolecular architectures by the cooperation of coordination bonds, hydrogen bonds and π⋯π interactions.

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Acknowledgments

We are grateful for the financial support of the National Natural Science Foundation of China (Grant No. 20471049, 20721001) National Basic Research Program of China (973 Program) 2007CB815301, NFFTBS (No. J0630429) and Xiamen University.

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Authors and Affiliations

  1. Department of Chemistry and The State Key Laboratory for Physical Chemistry of Solid Surfaces, College of Chemistry and Chemical engineering, Xiamen University, 361005, Xiamen, China

    Xiao-Bin Xu, Fei-Fei Lan, Shi-Yao Yang, Ming Li, Rong-Bin Huang & Lan-Sun Zheng

  2. North Fujian Vocational and Technical College, Jianyang, Fujian, China

    Xiao-Bin Xu

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  1. Xiao-Bin Xu
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Correspondence to Shi-Yao Yang.

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Xu, XB., Lan, FF., Yang, SY. et al. Two 3D Supramolecular Architectures Assembled With 1D or 2D Coordination Polymers by Cooperation of Coordination Bonds, Hydrogen Bonds and π···π Interactions. J Chem Crystallogr 40, 551–556 (2010). https://doi.org/10.1007/s10870-010-9695-9

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